Abstract:Laser surface melting of Ni based superalloys (alloys 600, 690 and 693) was carried out to study the effect of surface modification on the corrosion behaviour in simulated nuclear high level waste (HLW) and chloride medium. Surface characterisation was performed by optical microscopy, scanning electron microscopy and X-ray diffraction. The alloys exhibited cubic crystal system and cellular microstructure. Double loop electrochemical potentiokinetic reactivation test in 0?5M H 2 SO 4 containing 0?0001M KSCN sho… Show more
“…However, these AM technologies usually lead to a poor surface quality that does not meet the industrial requirements [66,67]. Currently, lots of methods exist to treat as well as improve the surface finishing of the AM as-built parts, and laser polishing is one of these [68]. Nevertheless, Inconel 718 is not easy to be processed by conventional machining processes mainly due to its low material removal rate and its high tool wear [69][70][71][72].…”
This paper provides a reliable state of the art of laser polishing process (LP), used to reduce surface roughness and to improve surface properties of additively manufactured metal parts. The motivation of this review and the introduction to the research topic are discussed in detail in the first part of the paper, then the fundamentals and the working principles of LP are exposed. A quantitative literature survey is also included, the main research streams are discussed, the most used laser sources and the most investigated materials are highlighted. The manuscript core is divided into five subchapters depending on the material to be polished: aluminium alloys, titanium alloys, steels, CoCr alloys and nickel alloys. Each of these discusses the laser adopted, the results obtained, the role of the process parameters and the physical phenomena ruling the process. The final section includes applications, advantages, direction of future work and main conclusions drawn.
“…However, these AM technologies usually lead to a poor surface quality that does not meet the industrial requirements [66,67]. Currently, lots of methods exist to treat as well as improve the surface finishing of the AM as-built parts, and laser polishing is one of these [68]. Nevertheless, Inconel 718 is not easy to be processed by conventional machining processes mainly due to its low material removal rate and its high tool wear [69][70][71][72].…”
This paper provides a reliable state of the art of laser polishing process (LP), used to reduce surface roughness and to improve surface properties of additively manufactured metal parts. The motivation of this review and the introduction to the research topic are discussed in detail in the first part of the paper, then the fundamentals and the working principles of LP are exposed. A quantitative literature survey is also included, the main research streams are discussed, the most used laser sources and the most investigated materials are highlighted. The manuscript core is divided into five subchapters depending on the material to be polished: aluminium alloys, titanium alloys, steels, CoCr alloys and nickel alloys. Each of these discusses the laser adopted, the results obtained, the role of the process parameters and the physical phenomena ruling the process. The final section includes applications, advantages, direction of future work and main conclusions drawn.
“…High temperature oxidation is classically performed using conventional heat treatments but laser processing of materials has extended the possibilities and is being increasingly used to optimize surface properties [25]. Among numerous techniques, laser surface melting (LSM) offers a significant potential for improvement of the corrosion behaviour [26][27][28][29][30][31][32][33]. For another application in the nuclear fuel cycle (storage of high level waste) LSM treatment of alloy 690 leads to an improved resistance to pitting corrosion due to chloride ions [27].…”
Section: At 285 • C the Diffusion Coefficient Of Ni In A Chromine Layer V Cr2o3mentioning
confidence: 99%
“…Among numerous techniques, laser surface melting (LSM) offers a significant potential for improvement of the corrosion behaviour [26][27][28][29][30][31][32][33]. For another application in the nuclear fuel cycle (storage of high level waste) LSM treatment of alloy 690 leads to an improved resistance to pitting corrosion due to chloride ions [27]. It has also been observed on chromium containing alloys that LSM can enrich the surface in chromium [28,34].…”
Section: At 285 • C the Diffusion Coefficient Of Ni In A Chromine Layer V Cr2o3mentioning
The surface of Ni-based alloy 690 was treated using a sub-microsecond pulsed laser in order to reduce the amount of nickel released when the surface is exposed to the primary cooling system of pressurized water nuclear reactors. A 2D array of laser treatment parameter sets was investigated. The results on sample surfaces was characterized using interferometric microscopy, Scanning Electron Microscopy (SEM), Glow Discharge Optical Emission Spectrometry (GDOES) and X-ray Photoelectron Spectrometry (XPS). The treatment leading to a continuous and defect-free chromine surface having the minimum nickel content over about the first two nanometers and no subsurface chromium depletion was selected for the nickel release test. This selection criterion proved to be very efficient as the total amount of nickel released in a standard qualification test using a simulated primary coolant was reduced, compared to a non-treated surface, by a factor of 7 during the heating phase and by a factor of 3.7 on average over the whole month-long test.
“…The bare metals are inclined to the highly aggressive corrosive medium, and it requires surface modification or coatings to enhance the surface properties. Researchers employ various thermal barrier coatings (TBCs) involving different coating processes, namely vacuum plasma spraying (VPS), low-pressure plasma spraying (LPPS), atmospheric plasma spraying (APS), high-frequency pulse detonation and high-velocity oxygen fuel spraying (HVOF) [3][4][5][6][7]. The plasma spray technique was found to be one of the best and versatile coating processes for thermal barrier coating materials [8].…”
The plasma-sprayed NiCr-Cr 2 O 3 and Al 2 O 3 -40 % TiO 2 powders are deposited as coating on nickelbased superalloy. The electrochemical polarisation studies were carried out with 1.0 M H 2 SO 4 solution as a corrosive medium. The corrosion current density of the coated sample was found to be decreased and exhibits better corrosion resistance than bare metal. The characterisation studies on the exposed sample result reveal that the bare metal has undergone severe intergranular attack and segregation on austenitic phase. The corrosion products formed are in the form of sulphides, and contribution of sulphur was noticed through EDS analysis.
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