1993
DOI: 10.1021/la00029a001
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Enhancement effect of micropore filling for supercritical methane by magnesia dispersion

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Cited by 48 publications
(44 citation statements)
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“…It can also be observed that H 2 adsorption in SWCNT reaches its saturation value below 1 bar. The data were fitted to the modified DR equation for micropore filling of supercritical gases [32,33], in order to derive a parameter (q st q¼1=e ) that characterizes the H 2 Table 3 e Textural properties of the carbon materials calculated from N 2 adsorption at 77 K. interaction with the materials. The results are presented in Table 4 and are in agreement with the observations described above.…”
Section: Low-pressure H 2 Adsorptionmentioning
confidence: 99%
“…It can also be observed that H 2 adsorption in SWCNT reaches its saturation value below 1 bar. The data were fitted to the modified DR equation for micropore filling of supercritical gases [32,33], in order to derive a parameter (q st q¼1=e ) that characterizes the H 2 Table 3 e Textural properties of the carbon materials calculated from N 2 adsorption at 77 K. interaction with the materials. The results are presented in Table 4 and are in agreement with the observations described above.…”
Section: Low-pressure H 2 Adsorptionmentioning
confidence: 99%
“…The micropore filling of N 2 and Ar vapor in micropores of ACF has been studied (14,15). Also the micropore filling of supercritical N 2 and CH 4 was studied by use of the high pressure measurement (16,17). However, no study on adsorption of supercritical Xe in carbon micropores has been reported as far as we know.…”
Section: Introductionmentioning
confidence: 99%
“…Metal oxide/hydroxidedeposited ACFs can be catalysts improving performance in reactions such as selective catalytic reduction of NO x using NH 3 [14], reduction of dissolved oxygen in water with hydrazine [15], and photocatalytic reaction [16]. They are also efficient adsorbents for supercritical gases such as NO [17][18][19] and CH 4 [20,21]. Kaneko et al have found that surface modification of ACFs by various kinds of metal oxides/hydroxides leads to an evident enhancement of CH 4 adsorptivity [20].…”
Section: Introductionmentioning
confidence: 99%
“…They are also efficient adsorbents for supercritical gases such as NO [17][18][19] and CH 4 [20,21]. Kaneko et al have found that surface modification of ACFs by various kinds of metal oxides/hydroxides leads to an evident enhancement of CH 4 adsorptivity [20]. Hattori et al reported that highly dispersed nickel oxides that remarkably enhance CH 4 adsorption form a special local structure on the carbon surface with respect to bulk powders [21].…”
Section: Introductionmentioning
confidence: 99%