Solar steam generation at the sterilization condition suffers from low efficiency, especially in passive solar thermal devices. We developed a stationary solar collector with a transparent aerogel layer to achieve efficient solar steam generation via thermal concentration. In field tests performed in Mumbai, India, the device generated steam at 100 C with 56% efficiency and successfully powered a sterilization cycle following the standard sterilization protocol. Our work shows the potential of solar thermal technology in steam generation and other applications.