Enhanced Photostability and Photoactivity of Ruthenium Polypyridyl-Based Photocatalysts by Covalently Anchoring Onto Reduced Graphene Oxide
Seán Hennessey,
Roberto González-Gómez,
Kathryn McCarthy
et al.
Abstract:Recentstudies toward finding more efficient ruthenium metalloligands for photocatalysis applications have shown that the derivatives of the linear [Ru(dqp) 2 ] 2+ (dqp: 2,6-di(quinolin-8-yl)-pyridine) complexes hold significant promise due to their extended emission lifetime in the μs time scale while retaining comparable redox potential, extinction coefficients, and absorption profile in the visible region to [Ru(bpy) 3 ] 2+ (bpy: 2,2′-bipyridine) and [Ru(tpy) 2 ] 2+ (tpy: 2,2′:6′,2″-terpyridine) complexes. N… Show more
This article demonstrates the synthesis of mixed ligand complexes of cis-[Co(tn)2(Rpy)Br]Br2via a mechanochemical approach. Their ferromagnetic properties and efficient electron transfer to Co(iii) using TiO2 under UV light are confirmed.
This article demonstrates the synthesis of mixed ligand complexes of cis-[Co(tn)2(Rpy)Br]Br2via a mechanochemical approach. Their ferromagnetic properties and efficient electron transfer to Co(iii) using TiO2 under UV light are confirmed.
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