Developing
photocatalysts with a high-efficiency charge separation
remains a challenge in the solar hydrogen production. Herein, we devised
and prepared a unique 2D/2D heterojunction of CuInS2/ZnIn2S4 nanosheets for solar hydrogen evolution. Structural
characterizations reveal that the CuInS2/ZnIn2S4 2D/2D heterojunction with lattice match consists of
the thin thickness of nanosheets and has a large interface contact
area, boosting charges transfer and separation. Benefiting from the
favorable 2D/2D heterojunction structure, the CuInS2/ZnIn2S4 2D/2D heterojunction photocatalyst with 5 wt
% CuInS2 yields the highest H2 evolution rate
of 3430.2 μmol·g–1·h–1. In addition, the apparent quantum efficiency of 5%CuInS2/ZnIn2S4 2D/2D heterojunction reaches 12.4%
at 420 nm, which is high among the ZnIn2S4-based
2D/2D heterojunctions. The enhanced photocatalytic H2 evolution
comes from the boosting charge separation. This work demonstrates
that a 2D/2D heterojunction provides a potential way for significantly
improving the solar hydrogen production performance of ZnIn2S4.