The production, processing, and transportation
of heavy crude oil
(HCO) is difficult because of its high viscosity. For practical applications,
information on the rheological behavior of HCO plays an important
role, especially in flow assurance investigations. In this work, six
different imidazolium ionic liquids (ILs) were tested for their effects
on the rheological behavior of HCO under high-pressure and high-temperature
conditions. The rheological studies were carried out at three different
pressures (0.1, 5, and 10 MPa) and four experimental temperatures
(298.15, 323.15, 348.15, and 373.15 K). The HCO + IL systems showed
favorable viscosity reductions of 26.5% and 31.5% for the systems
of HCO + 1-butyl-3-methylimidazolium chloride ([BMIM]+[Cl]−) and HCO + 1-octyl-3-methylimidazolium chloride ([OMIM]+[Cl]−), respectively, at 298.15 K and 0.1
MPa as compared to the pure HCO system. At 298.15 K and 0.1 MPa, the
yield stress of the HCO + IL systems was reduced by about 15–20%,
whereas when the temperature was increased to 373.15 K, the yield
stress decreased in the range of 25–30% as compared to that
of neat HCO. The viscoelastic moduli of the HCO sample at 0.1 MPa,
298.15 K, and about 1.5% strain were found to be G′ (storage modulus) ≈ 11 Pa and G″
(loss modulus) ≈ 7 Pa, indicating that the HCO sample was solidlike,
whereas for the HCO + IL systems, the G′ and G″ values were reduced to ∼7 and 3 Pa, respectively.
The crossover frequency of the HCO + IL systems was reduced to the
range of 25–30% as compared to that of pure HCO. From the various
measurements, it was observed that the addition of the ILs to the
HCO resulted in improved rheological properties compared to those
of the pure HCO system. Further, the results of the microscopic investigation
also supported the rheological studies, indicating that the addition
of the ILs helped to break the large flocculated structures of HCO
into smaller spheres. It was also observed that the IL with the longer
alkyl chain length provided greater efficiency in the viscosity reduction
with favorable viscoelastic behavior.