The current membrane materials used for oil–water
separation
suffer from low separation efficiency and poor durability, and membrane
contamination is also a key issue that must be addressed urgently.
In this paper, a superhydrophilic PANI/Ag/TA@PVDF composite membrane
with PANI-Ag NPs heterojunction structure was prepared via chelation
and reduction of Ag+ by tannic acid (TA) and in situ growth
of hydrochloric acid-doped polyaniline (PANI). TA endows the prepared
composite membrane with excellent superhydrophilicity and underwater
oleophobicity, remarkable oil–water separation capacity (the
separation efficiency of more than 97% for soybean oil), and extraordinary
antifouling properties. Notably, the range of photodegradation is
expanded from UV to visible light by the construction of a Schottky
heterostructure between PANI and Ag NPs, the photocatalytic degradation
ability of composite membrane for organic pollutants has been improved
obviously, and the degradation efficiency for crystal violet (CV)
is 97.9%. Considering these merits, the PANI/Ag/TA@PVDF composite
membrane provides an effective strategy to overcome the shortcomings
of existing membrane materials, presenting enormous potential in the
treatment and purification of oily wastewater.