2007
DOI: 10.1063/1.2431711
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Enhanced luminescence from catalyst-free grown InP nanowires

Abstract: The surface effects in the optical properties of catalyst-free grown InP nanowires are investigated. Both as-grown nanowires and nanowires treated with hydrofluoric acid are studied using low- and room-temperature continuous-wave and time-resolved photoluminescence measurements and transmission electron microscopy. It is shown that the room-temperature photoluminescence intensity is increased by two orders of magnitude after the surface treatment, and that there is also a significant increase in the double-exp… Show more

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Cited by 45 publications
(51 citation statements)
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“…[42][43][44][45][46][47][48][49][50][51][52][53][54][55] The inorganic-shell growth onto the core nanocrystals may not eliminate surface dangling bonds, and may also generate a nanocrystal system with different optical/electronic properties. However, proper passivation of the core material by an inorganic material of a different bandgap can also provide both effective elimination of any surfacerelated defect states and the confinement of charge carriers in the core material due to the band-offset potential.…”
Section: Introductionmentioning
confidence: 99%
“…[42][43][44][45][46][47][48][49][50][51][52][53][54][55] The inorganic-shell growth onto the core nanocrystals may not eliminate surface dangling bonds, and may also generate a nanocrystal system with different optical/electronic properties. However, proper passivation of the core material by an inorganic material of a different bandgap can also provide both effective elimination of any surfacerelated defect states and the confinement of charge carriers in the core material due to the band-offset potential.…”
Section: Introductionmentioning
confidence: 99%
“…Vapour-phase techniques such as molecular beam epitaxy and metal oxide chemical vapour deposition (MOCVD) [26][27][28][29][30][31][32][33][34] generally produce NWs on the pre-designed substrates [35]. There exists a limit on the physical size of the substrate and the number of substrates that may be processed through a single batch.…”
Section: Synthesis Of Indium Phosphide Nanowiresmentioning
confidence: 99%
“…These calculations are in part motivated by recent experimental results showing that the photoluminescence(PL) intensity in nanowires is strongly polarization dependent 8,52,[58][59][60][61][62] , including Si nanowires 63 . Nanowire polarization effects can arise from the dielectric mismatch at the wire surface 58 , electron-hole recombination selection rules [64][65][66] , as well as from the underlying WZ-type crystal structure [67][68][69][70][71][72] .…”
Section: Introductionmentioning
confidence: 99%