We
selectively improved the viewing angle characteristics and light
extraction efficiency of blue thermally activated delayed fluorescence
(TADF) organic light-emitting diodes (OLEDs) by tailoring a nanofiber-shaped
Si3N4 layer, which was used as an internal scattering
layer. The diameter of the polymer nanofibers changed according to
the mass ratio of polyacrylonitrile (PAN) and poly(methyl methacrylate)
(PMMA) in the polymer solution for electrospinning. The Si3N4 nanofiber (SNF) structure was fabricated by etching
an Si3N4 film using the PAN/PMMA nanofiber as
a mask, making it easier to adjust parameters, such as the diameter,
open ratio, and height, even though the SNF structure was randomly
shaped. The SNF structures exhibited lower transmittance and higher
haze with increasing diameter, showing little correlation with their
height. However, all the structures demonstrated a total transmittance
of over 80%. Finally, by applying the SNF structures to the blue TADF
OLEDs, the external quantum efficiency was increased by 15.6%. In
addition, the current and power efficiencies were enhanced by 23.0%
and 25.6%, respectively. The internal light-extracting SNF structure
also exhibited a synergistic effect with the external light-extracting
structure. Furthermore, when the viewing angle changed from 0°
to 60°, the peak wavelength and CIE coordinate shift decreased
from 20 to 6 nm and from 0.0561 to 0.0243, respectively. These trends
were explained by the application of Snell’s law to the light
path and were ultimately validated through finite-difference time-domain
simulations.