2016
DOI: 10.1016/j.memsci.2016.04.019
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Enhanced gas separation performance of mixed matrix membranes from graphitic carbon nitride nanosheets and polymers of intrinsic microporosity

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Cited by 111 publications
(45 citation statements)
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“…The enhancement in the mechanical properties observed for some of the MMMs can be attributed to the good dispersion and compatibility between the fillers and the PIM-1 polymer matrix. This consequently leads to a successful load-transfer between the continuous and the dispersed phases of the membranes [39][40][41]. In addition, the increase in elongation at break at lower alkyl-functionalized GO loading might be due to the intrinsic mechanical properties of graphene [42].…”
Section: Resultsmentioning
confidence: 99%
“…The enhancement in the mechanical properties observed for some of the MMMs can be attributed to the good dispersion and compatibility between the fillers and the PIM-1 polymer matrix. This consequently leads to a successful load-transfer between the continuous and the dispersed phases of the membranes [39][40][41]. In addition, the increase in elongation at break at lower alkyl-functionalized GO loading might be due to the intrinsic mechanical properties of graphene [42].…”
Section: Resultsmentioning
confidence: 99%
“…g‐C 3 N 4 is typically synthesized by thermal polymerization of precursors and their nanosheets are prepared by chemical exfoliation with strong acid, high‐temperature calcination under H 2 , or sonication‐assisted liquid exfoliation depending on the properties of the crude g‐C 3 N 4 . Unlike BN, owing to the small pores of g‐C 3 N 4 with a geometric diameter of 0.31 to 0.34 nm, 2D membranes of g‐C 3 N 4 have nanochannels as an extra pathway for the transport of small molecules …”
Section: Formation Of 2d Nanosheets and Their Composite Membranesmentioning
confidence: 99%
“…One way to stabilize the polymer matrix is by introducing several different kinds of fillers to design mixed matrix membranes (MMMs). Main examples for fillers that are used for MMMs are porous materials like MOFs, [101][102][103] carbon nitrides 104 but also microporous polymer networks [105][106][107] and related molecular fillers like organic cages (Fig. 6).…”
mentioning
confidence: 99%