Enhanced energy storage performance in (Pb0.858Ba0.1La0.02Y0.008)(Zr0.65Sn0.3Ti0.05)O3–(Pb0.97La0.02)(Zr0.9Sn0.05Ti0.05)O3 anti-ferroelectric composite ceramics by Spark Plasma Sintering

Zhang, Ling; Jiang, Shenglin; Fan, Botao; Zhang, Guangzu

doi:10.1016/j.jallcom.2014.09.171

Cited by 162 publications

(61 citation statements)

References 20 publications

(18 reference statements)

Supporting

Mentioning

Contrasting

Order By: Relevance

“…The maximum energy storage density obtained was 0.9 J/cm 3 , which was 300% larger than conventionally sintered ceramics. Zhang et al have reported the beneficial effects of spark plasma sintering (SPS) technique for improving energy storage density in (Pb 0.858 Ba 0.1 La 0.02 Y 0.008 )(Zr 0.65 Sn 0.3 Ti 0.05 )O 3 -(Pb 0.97 La 0.02 )(Zr 0.9 Sn 0.05 Ti 0.05 )O 3 (PBLYZST–PLZST) AFE ceramics [70]. It was reported that SPS is helpful to supress the diffusion behavior between the tetragonal and orthorhombic phases.…”

Section: Influence Of Other Factorsmentioning

confidence: 99%

Anti-Ferroelectric Ceramics for High Energy Density Capacitors

et al. 2015

View full text Add to dashboard Cite

With an ever increasing dependence on electrical energy for powering modern equipment and electronics, research is focused on the development of efficient methods for the generation, storage and distribution of electrical power. In this regard, the development of suitable dielectric based solid-state capacitors will play a key role in revolutionizing modern day electronic and electrical devices. Among the popular dielectric materials, anti-ferroelectrics (AFE) display evidence of being a strong contender for future ceramic capacitors. AFE materials possess low dielectric loss, low coercive field, low remnant polarization, high energy density, high material efficiency, and fast discharge rates; all of these characteristics makes AFE materials a lucrative research direction. However, despite the evident advantages, there have only been limited attempts to develop this area. This article attempts to provide a focus to this area by presenting a timely review on the topic, on the relevant scientific advancements that have been made with respect to utilization and development of anti-ferroelectric materials for electric energy storage applications. The article begins with a general introduction discussing the need for high energy density capacitors, the present solutions being used to address this problem, and a brief discussion of various advantages of anti-ferroelectric materials for high energy storage applications. This is followed by a general description of anti-ferroelectricity and important anti-ferroelectric materials. The remainder of the paper is divided into two subsections, the first of which presents various physical routes for enhancing the energy storage density while the latter section describes chemical routes for enhanced storage density. This is followed by conclusions and future prospects and challenges which need to be addressed in this particular field.

show abstract

Section: Influence Of Other Factorsmentioning

confidence: 99%

Anti-Ferroelectric Ceramics for High Energy Density Capacitors

et al. 2015

View full text Add to dashboard Cite

show abstract

“…[4][5][6][7][8][13][14][15][16][17][18] A lot of reports of high energy densities have been achieved on PLZST AFEs due to their excellent antiferroelectric behaviors. 4,7,[16][17][18] Recently, the highest W re of 6.4 J/cm 3 to date in ceramics has been demonstrated on PLZST based AFE ceramics. 16 However, the energy efficiency is usually less than 75% due to the large electrical hysteresis.…”

mentioning

confidence: 99%

“…4,7,[16][17][18] Recently, the highest W re of 6.4 J/cm 3 to date in ceramics has been demonstrated on PLZST based AFE ceramics. 16 However, the energy efficiency is usually less than 75% due to the large electrical hysteresis. 7,16,18 Besides, these reports are mostly focused on improving the energy density, with few aimed to explore the temperature stability.…”

mentioning

confidence: 99%

“…16 However, the energy efficiency is usually less than 75% due to the large electrical hysteresis. 7,16,18 Besides, these reports are mostly focused on improving the energy density, with few aimed to explore the temperature stability. Moreover, PLZST AFEs have a high Curie temperature (near 200 C), 7,15,19 which means the antiferroelectric phase may be capable to exist in a wide scope of temperature.…”

mentioning

confidence: 99%

See 1 more Smart Citation

Temperature-dependent stability of energy storage properties of Pb0.97La0.02(Zr0.58Sn0.335Ti0.085)O3 antiferroelectric ceramics for pulse power capacitors

Liu

Chen

Peng

et al. 2015

Applied Physics Letters

213

View full text Add to dashboard Cite

Published by the AIP PublishingArticles you may be interested in Effect of composition on the pressure-driven ferroelectric to antiferroelectric phase transformation behavior of (Pb0.97La0.02)(Zr1−x−ySnxTiy)O3 ceramics J. Appl. Phys. 116, 074107 (2014); 10.1063/1.4893372 Temperature-dependent energy storage properties of antiferroelectric Pb0.96La0.04Zr0.98Ti0.02O3 thin films Appl. Phys. Lett. The A-site driven phase transition procedure of (Pb0.97La0.02)(Zr0.42Sn0.40Ti0.18)O3 ceramics: An evidence from electronic structure variation Appl. Phys. Lett. 103, 192910 (2013); 10.1063/1.4829757 Enhanced polarization switching and energy storage properties of Pb0.97La0.02(Zr0.95Ti0.05)O3 antiferroelectric thin films with LaNiO3 oxide top electrodes

show abstract

“…5,6 These applications of AFE materials are designed from different AFE parameters if an electric field is applied, the AFE tetragonal (AFEtel) phase is transformed into its neighboring ferroelectric rhombohedral (FErh) phase. 7,8 To miniaturize the size and weight of energy storage devices, 9 AFE materials with high effective energy density are required. Since AFE materials have double hysteresis loops and the partial energy is exhausted during the depolarization process, the effective energy density is equal to the area between the polarization axis and the antiferroelectric to ferroelectric (AFE-to-FE) switching hysteresis loops.…”

Section: Introductionmentioning

confidence: 99%

Effect of Oxygen Annealing on the Electrical Properties of PBLZST Anti-ferroelectric Ceramics

Xue

Liu

et al. 2015

Journal of Elec Materi

Self Cite

View full text Add to dashboard Cite

The effect of oxygen annealing on the electrical properties of (Pb 0.97Àx Ba x La 0.02 )(Zr 0.6 Sn 0.32 Ti 0.08 )O 3 (PBLZST) anti-ferroelectric (AFE) ceramics has been investigated through measuring its phase structure, electric field-induced polarization and dielectric properties. The oxygen annealing process can significantly improve the stability of the AFE phase and decrease the dielectric constant peaks. The saturation polarization of the PBLZST samples annealed in O 2 increases gradually when x < 0.085, but it decreases when x > 0.085. Compared with the conventional sintering method, the hysteresis switch fields of samples annealed in O 2 maintains the consistent stability, and the dielectric constant peaks drop drastically and are simultaneously broadened, except at x = 0.095. The Curie temperature decreases greatly after oxygen annealing when x is smaller than 0.08, but increases slightly when x is greater than 0.08. When x = 0.085, the difference of c/a ratios between the samples processed by the two methods reaches a maximum of about 0.00614, and the increment of the saturation polarization is 7 lC/cm 2 .

show abstract

Enhanced energy storage performance in (Pb0.858Ba0.1La0.02Y0.008)(Zr0.65Sn0.3Ti0.05)O3–(Pb0.97La0.02)(Zr0.9Sn0.05Ti0.05)O3 anti-ferroelectric composite ceramics by Spark Plasma Sintering

Cited by 162 publications

References 20 publications

Anti-Ferroelectric Ceramics for High Energy Density Capacitors

Anti-Ferroelectric Ceramics for High Energy Density Capacitors

Temperature-dependent stability of energy storage properties of Pb0.97La0.02(Zr0.58Sn0.335Ti0.085)O3 antiferroelectric ceramics for pulse power capacitors

Effect of Oxygen Annealing on the Electrical Properties of PBLZST Anti-ferroelectric Ceramics

Contact Info

Product

Resources

About