Partial substitution of for has been studied on the high- superconducting materials of the Bi-Pb-Sr-Ca-Cu-O system (2223 phase). D.c. electrical resistivity, critical current density and a.c. magnetic susceptibility were measured by means of the standard four point probe technique and the inductance method, respectively. It was found that small substitution of enhanced slightly the critical transition temperature and decreased the critical current density. A significant change in the atomic concentration of each component with the substitution of was observed by XPS scan.