Enhanced catalytic activity of platinum decorated silica nanocrystals in rapid reduction of organic dyes

Daware, Krishna D.; Shinde, Rakesh N.; Khedkar, Chaitali V.; Patil, S. F.; Pandey, Ashok; Ashokkumar, Muthupandian; Gosavi, Suresh W.

doi:10.1016/j.chphi.2022.100109

Cited by 2 publications

(1 citation statement)

References 24 publications

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“…In the last two decades, adsorption and photocatalysis technologies have interestingly witnessed a breakthrough in their applications as an efficient method for contaminants remediation from aqueous solutions [37,38]. Thanks to material science and engineering, various materials have been discovered and explored for the execution of two applications.…”

Section: Introductionmentioning

confidence: 99%

Montmorillonite for Adsorption and Catalytic Elimination of Pollutants from Wastewater: A State-of-the-Arts Review

Zango

Garba

et al. 2022

Sustainability

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Clay minerals have been recognized as one of the cheap and effective materials for wastewater remediation. Among the various clay minerals, montmorillonite (MMT) has received much attention due to its wide availability, low-cost and promising properties such as high porosity, mechanical strength, and cation exchange capacity. Additionally, MMT has high swelling properties. These features make it an ideal material for wastewater remediation applications. In addition, it possessed good cationic exchange capacity, making it easier to interact with various molecules. MMT and its composites exhibited good selectivity and catalytic activity for contaminants elimination from wastewater. Surface modification and functionalization have been identified as a way to improve the MMT’s adsorptive performance and endow it with light and light-harnessing properties. Thus, MMT composites, especially metal and metal-oxide nanoparticles, have shown good adsorption and photocatalytic activity toward the elimination/mineralization of various contaminants such as dyes, pharmaceuticals, heavy metals, and other organic and inorganic species. As such, MMT and its composites can be adopted as potential materials for wastewater remediation.

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Section: Introductionmentioning

confidence: 99%

Montmorillonite for Adsorption and Catalytic Elimination of Pollutants from Wastewater: A State-of-the-Arts Review

Zango

Garba

et al. 2022

Sustainability

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Highly efficient catalytic reduction of organic dyes, Cr (VI) and 4‐nitrophenol, and photocatalytic degradation of MB by an inorganic–organic hybrid polyoxometalate

Liu,

Kong,

Fei

2024

Applied Organom Chemis

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It is urgent to remove various pollutants from the water environment. Therefore, an inorganic–organic hybrid polyoxometalate (POM) [PMoVI6MoV2VIV8O44{Co(2,2′‐bipy)2(H2O)}4]‐[PMoVI4MoV4VIV8O44{Co(2,2′‐bipy)2(H2O)}2]·4H2O (PMoVCo) was fully characterized by XRD, XPS, FTIR, SEM, BET and zeta potential techniques, and applied for the catalytic reduction of hazardous methylene blue (MB), methyl orange (MO), rhodamine B (RhB), Cr (VI) and 4‐nitrophenol (4‐NP) in aqueous media over NaBH4 under mild condition. The removal ratios were 99.6% (MB, 2.5 min), 97.0% (MO, 3.0 min), 92.5% (RhB, 2.0 min), 89.2% (Cr (VI), 2.0 min) and 89.6% (4‐NP, 2.5 min), respectively. The pseudo‐first‐order rate constants of the reactions were 1.992 min−1 (MB), 0.810 min−1 (MO), 1.768 min−1 (RhB), 1.186 min−1 (Cr (VI)) and 0.934 min−1 (4‐NP), respectively. Additionally, PMoVCo exhibited satisfactory catalytic activity for the photo‐Fenton‐like degradation of MB at neutral pH under visible light irradiation with a degradation rate up to 99.9% in 480 min. The results of the recycling experiment prove that PMoVCo has high catalytic reusability. Moreover, the possible mechanisms of the catalytic reduction and degradation processes were proposed. The catalytic activities of PMoVCo are better than other inorganic–organic hybrid POMs. All the results of this study indicate that PMoVCo has the potential to be a satisfactory catalyst for wastewater remediation via reduction or photocatalytic degradation.

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Enhanced catalytic activity of platinum decorated silica nanocrystals in rapid reduction of organic dyes

Cited by 2 publications

References 24 publications

Montmorillonite for Adsorption and Catalytic Elimination of Pollutants from Wastewater: A State-of-the-Arts Review

Montmorillonite for Adsorption and Catalytic Elimination of Pollutants from Wastewater: A State-of-the-Arts Review

Highly efficient catalytic reduction of organic dyes, Cr (VI) and 4‐nitrophenol, and photocatalytic degradation of MB by an inorganic–organic hybrid polyoxometalate

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