Engineering the Activity and Stability of the Zn-MOF Catalyst via the Interaction of Doped Zr with Zn
Xue Ye,
Chenxi Bai,
Peipei Zhang
et al.
Abstract:Metallic atoms within metal−organic framework (MOF) materials exhibit a distinctive and adaptable coordination structure. The three-dimensional (3D) pore configuration of MOFs enables the complete exposure of metal active sites, rendering them prevalent in various catalytic reactions. In this study, zinc (Zn) atoms within Zn-based MOF materials, characterized by an abundance of valence electrons, are utilized for the transesterification of dimethyl carbonate (DMC). Additionally, the introduction of zirconium (… Show more
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