Laser Applications to Chemical and Environmental Analysis 2002
DOI: 10.1364/lacea.2002.fb2
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Energy transfer in OH, CH and NO: Implications for quantitative LIF measurements

Abstract: Collision-induced processes (quenching, rotational and vibrational energy transfer, polarization scrambling) affect most LIF experiments. For OH, CH and NO, these processes are studied with picosecond resolution. Methods to obtain quench-free data and implications for flame measurements are discussed.

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“…The predicted lifetimes τ Ar and τ air are obtained from LASKIN simulations [23]. The fluorescence process after the excitation through the R 1 (4) line was simulated and the temporal profile of the total fluorescence was fitted with a single exponential decay to obtain the respective theoretical lifetime.…”
Section: Gas Mixing Estimationmentioning
confidence: 99%
“…The predicted lifetimes τ Ar and τ air are obtained from LASKIN simulations [23]. The fluorescence process after the excitation through the R 1 (4) line was simulated and the temporal profile of the total fluorescence was fitted with a single exponential decay to obtain the respective theoretical lifetime.…”
Section: Gas Mixing Estimationmentioning
confidence: 99%