Abstract:By using strong-field scheme, the complete d 5 energy matrix with D-n symmetry hits ' been constructed. Then, by dia.gona.liza.tion of this matrix at normal and various pressures, the whole energy spectrum [including the ground-state zero-field-splitting (GSZFS)], its PS and the g factor of the ground state for ZnS:Mn 2+ have uniformly been calculated. According to the eigenfunctions and PS, the new assignments of five absorption bands have been given. The variation of tetragonal field with pressure makes a ma… Show more
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