Energy-saving technology of styrene unit based on mechanical vapor recompression coupled with organic Rankine cycle process

Yang, De‐Ming; Li, Tao; Leng, Bingqin

doi:10.1080/15567036.2020.1821127

Cited by 2 publications

(1 citation statement)

References 24 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…As one of the most fundamental upstream raw materials in polymer science and technology, styrene monomer (SM) is widely employed for synthesizing various resins, such as acrylonitrile butadiene styrene resin, high-impact polystyrene, and styrene maleic anhydride resin . In recent research studies, the ethylbenzene (EB) dehydrogenation process has an outlet stream with a close ratio of EB and SM after the feed flow passes through the reactor. , It can be predicted that the reflux ratio (RR) in an EB/SM distillation column will be enormous due to the close boiling point of this binary system. − A higher RR means more energy loss, so finding an energy-efficient process is of great significance.…”

Section: Introductionmentioning

confidence: 99%

Optimization of EB/SM Distillation Processes Based on Divided Wall Columns in a PO/SM Process with a Chaos Differential Evolution Algorithm

et al. 2022

View full text Add to dashboard Cite

As an important chemical raw material, styrene has a high price because of its high energy consumption for separation. This article focuses on the styrene separation unit in a practical propylene oxide/styrene monomer process, and divided wall columns (DWC) are used for process optimization. Four DWC models are evaluated in terms of both economics based on the minimum total annual cost (TAC) and operability based on degrees of freedom. Differential evolutionary (DE) algorithms are used to optimize the parameters for each case study. In the process of finding the minimum TAC, the traditional DE often falls into local solutions and has low efficiency. In order to solve this problem, we propose chaotic sequences in DE algorithms to generate variables with ergodicity, which improves the optimization efficiency. Compared with the conventional process, Wright’s fully thermally coupled DWC (FTC) and Agrawal’s liquid-only transfer DWC (ALT) can save 21.36 and 10.14% TAC, respectively, but ALT has 2 more degrees of freedom than FTC. The FTC has the best economic efficiency, while the ALT strikes a balance between operability and economics.

show abstract