The needs for sustainable development and energy efficient
manufacturing
are crucial in the development of future composite materials. Out-of-oven
(OoO) curing of fiber-reinforced composites based on smart conductive
polymers reduces energy consumption and self-regulates the heating
temperature with enhanced safety in manufacturing, presenting an excellent
example of such energy efficient
approaches. However, achieving the desired curing processes, especially
for high-performance systems where two-stage curing is often required,
remains a great challenge. In this study, a ternary system consisting
of graphene nanoplatelets/HDPE/PVDF was developed, with a double positive
temperature coefficient (PTC) effect achieved to fulfill stable self-regulating
heating at two temperatures (120 and 150 °C). Systematic studies
on both single and double PTC effects were performed, with morphological
analysis to understand their pyroresistive behaviors. Compared to
the oven curing process, up to 97% reduction in the energy consumption
was achieved by the ternary system, while comparable thermal and mechanical
properties were obtained in the carbon fiber/epoxy laminates. This
work presents a new route to achieve OoO curing with two-stage self-regulating
heating, which can be utilized in many high-performance composite
applications.