“…On the basis of our previous work, by further considering the concentration of water molecules in different regions, two typical H 2 WO 4 (100) surfaces, with and without the top water layer, were considered as the possible prototypes for water‐rich and water‐poor zones on the surface, respectively (Figure S23 and Table S2, Supporting Information). [ 22 ] On the two typical H 2 WO 4 (100) surfaces, several isolated Pt anchoring sites were constructed and the related energies were calculated. It is interesting to note that, in the water‐rich zone, the isolated Pt atom prefers to occupy the bridge site between one oxygen atom from top layer water and one neighboring oxygen atom from top W−O polyhedra, denoted as Pt−2O (Figure S24, Supporting Information), while in the water‐poor zone, the isolated Pt atom coordinates three neighboring oxygen atoms from W−O polyhedra, denoted as Pt−3O (Figure S25, Supporting Information).…”