“…This process is very similar to the one of the van der Waals liquid-gas transition. Later, by treating the negative cosmological constant as the pressure and the physical volume enclosed by the black hole horizon as its thermodynamical conjugated quantity, and identifying the black hole mass as enthalpy instead of internal energy, the black hole thermodynamic is re-studied in the extended phase space that includes the pressure and volume [3,4,5,6], and the first law agrees with the corresponding Smarr relation [7,8,9]. Further, first attempts to study the phase structure in the pressure-volume, P -V , diagram was made for the charged Reissner-Nördstrom (RN) anti-de Sitter (AdS) black hole with fixed charge and the van der Waalslike phase transition was observed in [10].…”