“…Solar PVT is a comprehensive solar technology that integrates PV power generation and thermal (T) routes for utilization of residual heat from PV cells. In a typical PVT device, PV module is located before the thermal module, and electricity is first extracted out of the incident sunlight via the PV module, while the rest of the nonextractable solar energy is passed onto the thermal module in the form of heat for driving thermal cycles directly [9,10] or thermochemical reactions followed by thermal cycles for power generation [5,[11][12][13]. Among them, solar photovoltaic-thermochemical (PVTC) power generation systems with thermochemical reactions of fossil fuels offer distinct advantages over conventional ones with direct thermal cycles, such as high efficiency, stable power output, high solar share, low CO 2 emission, excellent energy storage capability, and round-the-clock service capabilities [13], among which certain features (e.g.…”