Abstract:We report a mass spectrometry study of the interaction between three representative Au(I) catalysts containing the ligands L = JohnPhos (2-biphenylyl[bis(2-methyl-2-propanyl)]phosphine), TPP (PPh3, triphenylphosphine), the N-heterocyclic carbene IPr (carbene form of 1,3-bis(2,6-diisopropylphenyl)-2,3-dihydro-1H-imidazole), and 27 organic molecules S (substrates) bearing organic functionalities often present in reactants (alkenes, alkynes, allenes, enol ethers, aldehydes, ketones, epoxides). An experimental sca… Show more
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