Energetic transition metal complexes based on 1‐allylimidazole and nitrocyanamide: Syntheses, characterizations and catalytic performances on the thermal decomposition of ammonium perchlorate
Yuhong Yuan,
Yinsheng Huang,
Mingcheng Ge
et al.
Abstract:To explore combustion catalysts for solid propellants, four novel energetic coordination compounds were prepared with the anion of nitrocyanamide (NCA) as the ligand and 1‐allyl‐imidazole (AIM) as the ligand, and transition metals Mn, Co, Ni, and Cu as the central ions. The structures of these compounds were [Mn(AIM)4] (NCA)2 (1), [Co(AIM)4](NCA)2 (2), [Ni(AIM)4](NCA)2 (3), [Cu(AIM)4](NCA)2 (4). The results showed that all of the compounds possessed high energy density, and compound 2 had a mass energy density… Show more
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