Encapsulation of shear thickening fluid as an easy-to-apply impact-resistant material

Huo

et al. 2019

The orifice coagulation bath method is proposed to encapsulate shear thickening fluid (STF) to form STF capsules, in an attempt to improve the combination of STF and the matrix as well as strengthen the flexibility and stability of the STF composites. By varying the calcium chloride concentration (10, 20 mg/ml), sodium alginate concentration (5, 7, 10 mg/ml) and the surfactant dosage (10%, 20%, 30%), optimal preparation conditions were studied, considering the capsule strength and encapsulation rate. The capsules were also characterized using a scanning electron microscope (SEM), Fourier transform infrared spectroscopy (FTIR) and a thermogravimetric analyzer (TGA). The results show that the optimal solution for the preparation of the capsules is composed of 30% surfactant, 10 mg/ml mass concentration of CaCl2, and 10 mg/ml mass concentration of sodium alginate. The rough surface and porous interior was observed by SEM. The average diameter of the capsules was 1.93 mm. The TGA curves indicate an improvement on the capsule thermal stability. This study thus provides a promising STF capsule preparation method.

Section: Introductionmentioning

confidence: 99%

Section: Introductionmentioning

confidence: 99%

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Investigation of the Shear Thickening Fluid Encapsulation in an Orifice Coagulation Bath

Huo

et al. 2019

“…The encapsulation of STF is rarely studied. Zhang et al successfully encapsulated STF and yielded double-layered capsules via interfacial polymerization, through which the cortex is polymerized from polyethyleneimine (PEI), diisocyanate prepolymer, and toluene [13]. They used the two-step aggregation method, thereby increasing the operability of STF [14].…”

Section: Introductionmentioning

confidence: 99%

Characteristics, Compression, and Buffering Performance of Pomelo-Like Hierarchical Capsules Containing Shear Thickening Fluid

Huo

et al. 2019

In this study, a double-walled and pomelo-like hierarchical shear thickening fluid (STF) is successfully encapsulated using the simple and environment-friendly calcium alginate encapsulation technique by instilling STF into sodium alginate (SA) and crosslinking by calcium chloride solution. The encapsulated STF has a pomelo-like structure with a shell thickness of 2.9 μm and core pores with a size of 21.43 μm. The effect of the size of STF capsules (2.10, 1.89, 1.86, 1.83, 1.73, and 1.63 mm) is explored in terms of thermal stability, swelling capacity, mechanical property, and release performance. The buffering performance of different sizes of STF-containing capsules is also investigated. The pomelo-like STF capsules can withstand a processing temperature of 250 °C. With a decrease in particle size, the compression strain energy slowly increases first and then rapidly enhances. The kinetic release of pomelo-like STF capsules conforms to Fickian diffusion. STF-containing capsules with a diameter of 1.83 mm present the greatest thermal stability, the highest STF amount, the maximum swelling coefficient, and the fastest kinetic diffusion. STF-containing capsules also have an improved buffering performance in PU foam. This capsule has the best comprehensive performance and can adapt to diversified applications, such as personnel armor and other protective sports equipment.

“…STF is a specific type of non-Newtonian fluid whose viscosity increases dramatically once the external shear rate or applied loading is beyond a critical value [9,10]. This smart fluid has a reversibility, which transforms from a liquid to solid-like state when subjected to high-speed impact, and returns to the initial liquid state when the impact stress disappears [11].…”

Section: Introductionmentioning

confidence: 99%

Shear-Thickening Fluid Using Oxygen-Plasma-Modified Multi-Walled Carbon Nanotubes to Improve the Quasi-Static Stab Resistance of Kevlar Fabrics

Wang

et al. 2018

The excellent mechanical property and light weight of protective materials are vital for practical application in body armor. In this study, O2-plasma-modified multi-walled carbon nanotubes (M-MWNTs) were introduced into shear-thickening fluid (STF)-impregnated Kevlar woven fabrics to increase the quasi-static stab resistance and decrease the composite weight. The rheological test showed that the addition of 0.06 wt. % M-MWNT caused a marked increase in the peak viscosity from 1563 to 3417 pa·s and a decrease in the critical shear rate from 14.68 s−1 to 2.53 s−1. The storage modulus (G′) and loss modulus (G″) showed a higher degree of abrupt increase with the increase of shear stress. The yarn pull-out test showed that the yarn friction of M-MWNT/STF/Kevlar fabrics was far superior to the original fabrics. Importantly, under similar areal density, the M-MWNT/STF/Kevlar fabrics could resist 1261.4 N quasi-static stab force and absorb 41.3 J energy, which were much higher than neat Kevlar fabrics. The results of this research indicated that quasi-static stab resistance was improved by M-MWNTs, which was attributed to the excellent shear-thickening effect and the high yarn friction. Therefore, M-MWNT/STF/Kevlar fabrics have a broad prospect in the fields of body protection.