2018
DOI: 10.1038/s41929-018-0030-8
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Encapsulating highly catalytically active metal nanoclusters inside porous organic cages

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Cited by 355 publications
(241 citation statements)
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“…Among numerous nonprecious materials, the composites composed of earth‐abundant transition metals (e.g., Fe, Co, Ni, Mn, and Cu) and N‐doped carbonaceous materials (TMs/NC) with excellent catalytic stability have been broadly viewed as a class of promising candidates owing to the unique d electron orbital of TMs and the strong TM‐N/C chemical bonding between TMs and NC . However, its electrocatalytic activities are still unsatisfactory . Up to now, numerous investigations have been devoted to enhancing the electrocatalytic activities of TMs/NC by tuning the structures and components, including increase the number of active sites and boost the intrinsic activity .…”
Section: Introductionmentioning
confidence: 99%
“…Among numerous nonprecious materials, the composites composed of earth‐abundant transition metals (e.g., Fe, Co, Ni, Mn, and Cu) and N‐doped carbonaceous materials (TMs/NC) with excellent catalytic stability have been broadly viewed as a class of promising candidates owing to the unique d electron orbital of TMs and the strong TM‐N/C chemical bonding between TMs and NC . However, its electrocatalytic activities are still unsatisfactory . Up to now, numerous investigations have been devoted to enhancing the electrocatalytic activities of TMs/NC by tuning the structures and components, including increase the number of active sites and boost the intrinsic activity .…”
Section: Introductionmentioning
confidence: 99%
“…[60][61][62][63][64] Generally, the hydrogen release rate from these LHSMs relies on the catalytic systems. [60][61][62][63][64] Generally, the hydrogen release rate from these LHSMs relies on the catalytic systems.…”
Section: Wwwadvancedsciencenewscommentioning
confidence: 99%
“…[65] The first synthesis of AB was reported in 1955. [68] Since the first report of AB hydrolysis using metal nanoparticle catalysts by our group in 2006, [69] a large number of studies have been performed by many groups to prepare MNPs with good dispersion, controlled sizes, and morphologies on different supports to achieve high-efficient catalysis for AB hydrolysis (1) [59][60][61][62][63] H NBH aq 2H O l NH BO aq 3H g [68] Since the first report of AB hydrolysis using metal nanoparticle catalysts by our group in 2006, [69] a large number of studies have been performed by many groups to prepare MNPs with good dispersion, controlled sizes, and morphologies on different supports to achieve high-efficient catalysis for AB hydrolysis (1) [59][60][61][62][63] H NBH aq 2H O l NH BO aq 3H g…”
Section: Ammonia Borane (Ab) Hydrolysismentioning
confidence: 99%
“…Metal–organic polyhedra (MOPs) as crystalline coordination materials that are constituted by metal ions and organic ligands . Owing to their unique features, such as permanent porosity and unsaturated metal centers, MOPs have shown great potential for applications in drug delivery, gas adsorption and storage, chemical sensors, and catalysis . As a common ligand isophthalic acid and its corresponding derivatized ligands have been widely used to prepare MOP materials .…”
Section: Introductionmentioning
confidence: 99%