Enantioselective Allylboration of Acetylene: A Versatile Tool for the Stereodivergent Synthesis of Natural Products
Andrés M. Álvarez‐Constantino,
Andrea Chaves‐Pouso,
Martín Fañanás‐Mastral
Abstract:Efficient catalytic methods that allow the use of simple and abundant chemical feedstocks for the preparation of synthetically versatile compounds are central to modern synthetic chemistry. Acetylene is a basic feedstock with a remarkable production over one million tons per year, although it is underutilized in the stereoselective synthesis of fine chemicals. Here we report a facile catalytic multicomponent reaction that allows for the enantio‐ and diastereoselective allylboration of acetylene gas. This proce… Show more
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