Emulsion Polymerization of Plant Oil-Based Acrylic Monomers: Resourceful Platform for Biobased Waterborne Materials

Kohut, Ananiy; Voronov, Stanislav; Demchuk, Zoriana; Kirianchuk, Vasylyna; Kingsley, Kyle; Shevchuk, Oleh; Voronov, Аndriy

doi:10.1021/bk-2020-1372.ch003

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Vegetable-oil- and Lipid-based Polymers1

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2023

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“…Many characteristics can change the physicochemical properties of these oils such as the stereochemistry of the double bonds, the degree of unsaturation and the length of the fatty acid chains 34,35 and can affect the thermochemical, physical and mechanical properties of the final bio-based polymers. 36 In addition, the length of the fatty acid chain influences the hydrophobicity of the bio-based monomers, which is an important parameter in radical polymerization in aqueous dispersed media ( e.g. ab initio emulsion polymerization of very hydrophobic monomers is usually problematic).…”

Section: Vegetable-oil- and Lipid-based Polymersmentioning

confidence: 99%