Employing supramolecular chemistry strategies for the separation of mixtures of anisole and bromoanisole isomers
Benita Barton,
Ulrich Senekal
Abstract:In the present work, host compounds trans-9,10-dihydro-9,10-ethanoanthracene-11,12-dicarboxylate (H1), trans-α,α,α’,α’-tetraphenyl-9,10-dihydro-9,10-ethanoanthracene-11,12-dimethanol (H2) and trans-α,α,α’,α’-tetra(p-chlorophenyl)-9,10-dihydro-9,10-ethanoanthracene-11,12-dimethanol (H3) were assessed for their host ability for anisole (ANI) and 2-, 3- and 4-bromoanisole (2-, 3- and 4-BA). It was demonstrated that H3 formed complexes with each of these guest species, while H1 and H2 only possessed the ability to… Show more
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