The emission of polycyclic aromatic hydrocarbons (PAHs) during start-up, burning, and burn-out were determined for four municipal solid waste MSW incinerators. During start-up conditions, PAH concentrations were shown to be high due to unstable combustion. A positive correlation was seen between PAH concentrations and the organic carbon content of the dust.This study was conducted to examine the emission behaviors of PAHs according to furnace type and to measure emissions during the combustion cycle. The organic carbon in the dust, as well as PAH emissions, during three combustion periods were determined for four MSW incinerators. PAHs were high during start-up because of incomplete combustion at low temperature. In the fluidized-bed incinerator, PAHs were high because combustion in the fluidized bed, was more unstable than in the step grate. A batch fluidized bed showed particularly higher concentrations compared to a continuous fluidized bed, owing to less stable combustion. Organic carbon in the dust was normally highest during start-up and lowest during burning. Continuous incinerators with longer operation periods showed higher emission rates during burning. This parameter for the batch-type fluidized bed increased during start-up and burn-out.
IMPLICATIONSPAH emissions from MSW incinerators can be controlled better by improving operating conditions. This study was conducted to examine the emission behavior of PAHs according to furnace type and to measure emissions during the combustion cycle. The results of this study suggest that PAHs are high during start-up because of incomplete combustion at low temperature. In the fluidized-bed incinerator, PAHs are high because combustion in fluidized bed is more unstable than in the step grate. A batch fluidized bed shows particularly higher concentrations compared to a continuous fluidized bed, owing to less stable combustion.
INTRODUCTIONPolycyclic aromatic hydrocarbons (PAHs) are produced in incinerators during the burning of municipal solid waste (MSW). The emission of PAHs caused by MSW is determined by waste composition, furnace temperature, and excess air. 1-8 These emissions may be affected by operating conditions since an incinerator is always operating under start-up, burning, and burn-out.During start-up conditions, PAH concentrations have been shown to be high, due to unstable combustion. 4,[9][10][11] A positive correlation between PAH concentrations and the organic carbon content of the dust has been demonstrated. 12,13 PAH emissions from MSW incinerators can be controlled better by improving operating conditions. For this purpose, PAH emissions under various operating conditions during the combustion cycle (start-up, burning, and burn-out periods) should be studied.This study was conducted to examine the emission behaviors of PAHs according to furnace type and to measure emissions throughout the combustion cycle. The organic carbon content in the dust, as well as PAH emission rates under the three operating conditions, were determined.