performance and relatively low cost have been demonstrated as a leading candidate for numerous applications in energy harvesting and self-powered sensing. [1][2][3][4][5] It plays an increasingly important role with the fast depletion of fossil fuels. As an energy harvester, the output characteristic of the TENGs is the key consideration, which involves two main aspects: the surface charge density [6][7][8] and the output impedance. [9,10] Till now, studies have been conducted on the improvement of the surface charge density, such as surface functionalization techniques including micropatterning surface, [11][12][13][14][15][16][17][18][19][20] plasma treatment, [21] or adding chemical functional groups. [22][23][24][25] Especially substantial researches on the TENGs have concentrated on making triboelectric layers into both micro-and nanoscale to achieve increased surface areas and roughness. [26] However, there is a lack of effective means to reduce the output impedance.Plasmonic energy conversion proposed as a high efficiency scheme to electron-hole separation opens up a wide range of applications in the field of subwavelength optics, [27] data storage, [28] nonlinear optics, [29] solar cells, [30] and Adv. Energy Mater. 2019, 9, 1902725 www.advenergymat.de www.advancedsciencenews.com