Elucidation of the Fundamental Properties of Thiolate-protected Metal Clusters by HPLC

Abstract

Kornberg 4-4-Mercaptobenzoic Acid, p-MBA 102 Au 102 (p-MBA) 44 X 21 HPLC Au n (SR) m Au n-x M x (SR) m 3 1

Alkynyl- and phosphine-ligated quaternary Au2Ag2 clusters featuring an Alkynyl-AuAg motif for multicomponent coupling

“…With the developments in nanotechnology, some big molecule-like metal nanoclusters having different core structures and sizes have been determined by X-ray single crystal diffraction. [10][11][12][13][14] For the application of newly discovered materials, there is no doubt that the insight into their nanostructure at the atomic level is helpful for the understanding of the relationship between structures and properties, which is an indispensable step for exploring the application of these nanomaterials.…”