Elements of Transition-State Theory in Relation to the Thermal Dissociation of Selected Solid Compounds
Andrzej Mianowski,
Tomasz Radko,
Rafał Bigda
Abstract:An analysis was carried out on the thermal dissociation of selected inorganic salts according to Transition-State Theory (TST). For this purpose, two possibilities were compared in the context of rate constants: in the first case using the Arrhenius constant directly from TST, and in the second, using the thermodynamic equilibrium constant of the reaction/process of active state formation. The determined relationships are presented in the form of temperature profiles. It was established that TST applies to rea… Show more
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