Elementary Reaction Kinetic Model of an Anode-Supported Syngas Fueled Solid Oxide Fuel Cell Considering the Carbon Deposition Effect

Abstract

A one-dimensional transient elementary reaction kinetic model of an anode supported solid oxide fuel cell (SOFC) fueled with syngas is developed considering the carbon deposition effect. This model incorporates the coupling effect of heterogeneous elementary chemical and electrochemical reactions, the electrode microstructure and the charge, and mass transport processes. The model is validated by both experimental I-V curves and electrochemical impedance spectra. The simulation results agree reasonably well with the experimental data. The numerical results of carbon deposition simulation indicate that the surface carbon coverage can be decreased by increasing the operating temperature and reducing the carbon dioxide, methane, or carbon monoxide in the fuel.

Ni coarsening and performance attenuation prediction of biomass syngas fueled SOFC by combining multi-physics field modeling and artificial neural network

“…As a result, the reaction activity is reduced [25]. It is noteworthy that there have been related reports on the carbon deposition phenomenon from the perspective of experiments and simulations [25][26][27][28]. It was summarized that the operating conditions can suppress the carbon deposition phenomenon.…”