Electrosynthesis of poly(aniline-co-azure B) for aqueous rechargeable zinc-conducting polymer batteries

Chen, Chuanxiang; Gan, Zhengyang; Xu, Chao; Lu, Lin; Liu, Yinqiu; Gao, Yuhua

doi:10.1016/j.electacta.2017.08.195

Cited by 65 publications

(32 citation statements)

References 41 publications

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“…For example, Chen et al. reported a novel poly(aniline‐ co ‐azure B) (PANAB) copolymer by incorporating redox‐active azure B into the main chain of PANI through co‐electropolymerization and employed it as a cathodic material for a rechargeable aqueous Zn–organic battery . The PANAB electrode exhibits both good electrical conductivity and high electrochemical activity, benefiting from the incorporation of the phenothiazine ring with redox activity into the conjugated backbone.…”

Section: Recent Advances In Organic Cathode Materialsmentioning

confidence: 99%

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Organic Cathode Materials for Rechargeable Zinc Batteries: Mechanisms, Challenges, and Perspectives

et al. 2020

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Section: Recent Advances In Organic Cathode Materialsmentioning

confidence: 99%

Section: Recent Advances In Organic Cathode Materialsmentioning

confidence: 99%

Organic Cathode Materials for Rechargeable Zinc Batteries: Mechanisms, Challenges, and Perspectives

et al. 2020

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“…Organic compounds have been investigated as rechargeable AZIB electrodes with the merits of sustainable, low toxic, and biodegradable . Here, we list electrochemical performances reported organic compounds in AZIBs recently, including polyanilinecalix(PANI), poly(benzoquinonyl sulfide) (PBQS), pyrene‐4,5,9,10‐tetraone (PTO), tetrachloro‐1,4‐benzoquinone ( p ‐chloranil), calix [4]quinone (C4Q), 9,10‐di(1,3‐dithiol‐2‐ylidene)‐9,10‐dihydroanthracene(exTTF), poly(aniline‐ co ‐azure B) (PANAB), etc . Table 5 illustrates the working window and electrochemical properties of the typically reported organic compound cathode materials.…”

Section: Organic Compoundsmentioning

confidence: 99%

Recent Advances and Prospects of Cathode Materials for Rechargeable Aqueous Zinc‐Ion Batteries

Chen

Mai

2019

Adv Materials Inter

200

124

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attention. [9][10][11] AZIBs are considered as one of the most ideal candidates for largescale energy storage owing to their following advantages:i) The excellent properties of zinc: According the data in Table 1, the abundance of zinc in the earth's crust is 79 ppm, and ranks fourth in the world metal production, so zinc has a low market price. Zn metal anode has good electrical conductivity (5.91 µΩ cm), high volumetric energy density (5851 mAh cm −3 ), high theoretical capacity (819 mAh g −1 ), and relatively low redox potential (−0.76 V vs standard hydrogen electrode) which is more suitable in aqueous solution. In addition, multivalent zinc ion can transfer two electrons to facilitate more energy storage than the univalent batteries. [12] At the same time, the ionic radius of zinc ions is 0.74 Å, which is smaller than that of sodium ions (1.02 Å) and close to that of lithium ions (0.69 Å). Moreover, zinc is the essential trace element for human body. [9] In brief, Zn has the superiorities of low cost, low-toxicity, abundant resource, easily recycle, and environmental friendliness.ii) The higher ionic conductivity and safety of aqueous electrolytes: The aqueous electrolytes offer two orders of higher magnitude ionic conductivities (≈1 S cm −1 ) than that of organic electrolytes (≈10 −2 -10 −3 S cm −1 ), so aqueous battery usually has higher power density. [3,13] Meanwhile, the organic electrolytes are usually toxic and flammable, while the aqueous electrolytes are nontoxic and safe, which can mitigate the environmental disruption and recycling costs. iii) The facile assembly process: AZIBs can be assembled in the air condition owing to the stability of zinc anode and aqueous electrolyte. Compared with the batteries assembled in the inert-gas glove box, the manufacturing costs of ZIBs are greatly reduced. The facile manufacture and recycling of AZIBs is an important advantage in the large-scale storage applications.Combining the above advantages, low-cost, safe, and green next-generation AZIBs are suitable specifically for large-scale stationary storage applications. So far, AZIBs are still at the infancy stage. The related researches mainly focused on cathode materials. We count the publication numbers of the reported cathodes for AZIBs in the period from 2012 to February 2019 (1, Supporting Information). As illustrated in Figure 1a, the number of annual publications on cathodes for AZIBs continues to increase rapidly in the recent years. However, in the preliminary stage, Electrochemical energy storage devices will definitely play a vital role in the future energy landscape of the world. The innovation of electrode materials is a key task for the breakthrough of present bottleneck faced by electrochemical energy storage devices. Aqueous zinc-ion batteries (AZIBs) are gaining rapid attention, and they offer tremendous opportunities to explore the low-cost, safe, and next-generation green batteries for large-scale stationary storage applications. In this review, the authors aim to give a comprehensive overview ...

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“…Conducting polymers materials (CPM) having hybrid π-conjugated bonds has attracted interest from many researchers in scientific and industrial fields in recent times. Conductive polymeric, such as polyaniline, polypyrrole, poly(p-phenylene) and polythiophene, have usually been applied in technological investigations and in several applications as rechargeable batteries [14,15], sensors [16] diodes, microelectronic devices and in transistors and [17,18]. Amongst the CPM, PANI receiving a great deal of attention due to their good environmental stability, simple synthesis, ability to dope with protonic acids, and the being of amine groups in its structure and higher electrical conductivity [19].…”

Section: Introductionmentioning

confidence: 99%

Removal of methyl orange from from aqueous solutions using of PANI and PANI@Activated Carbon: Preparation, characterization, regeneration and comparative study

Bekhoukh

Moulefera

Zeggai

et al. 2021

Preprint

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This work investigated the elimination of Methyl Orange (MO) using a new adsorbent prepared from Activated Carbon (AC) with polyaniline reinforced by a simple oxidation chemical method. The prepared materials were characterized using XRD, TGA, FTIR and nitrogen adsorption isotherms. Furthermore, PANI@CA highest specific surface area values (near 332 m2.g− 1) and total mesoporous volume (near 0.038 cm3.g− 1) displayed the better MO removal capacity (192.52 mg.g− 1 at 298 K and pH 6.0), which is outstandingly higher than that of PANI (46.82 mg.g− 1). Besides, the process's adsorption, kinetics, and isothermal analysis were examined using various variables such as pH, MO concentration and contact time. To pretend the adsorption kinetics, various kinetics models, the pseudo first- and pseudo second- orders, were exercised to the experimental results. The kinetic analysis revealed that the pseudo second order rate law performed better than the pseudo first order rate law in promoting the formation of the chemisorption phase. In the case of isothermal studies, an analysis of measured correlation coefficient (R2) values showed that the Langmuir model was a better match to experimental results than the Freundlich model. By regeneration experiments after five cycles, acceptable results were observed.

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Electrosynthesis of poly(aniline-co-azure B) for aqueous rechargeable zinc-conducting polymer batteries

Cited by 65 publications

References 41 publications

Organic Cathode Materials for Rechargeable Zinc Batteries: Mechanisms, Challenges, and Perspectives

Organic Cathode Materials for Rechargeable Zinc Batteries: Mechanisms, Challenges, and Perspectives

Recent Advances and Prospects of Cathode Materials for Rechargeable Aqueous Zinc‐Ion Batteries

Removal of methyl orange from from aqueous solutions using of PANI and PANI@Activated Carbon: Preparation, characterization, regeneration and comparative study

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