“…For the samples of MNF 1 and MNF 2 , a large number of individual nanoparticles Fe 3 O 4 are anchored strongly and distributed homogenously on the surface of nanofiber, unlike in previously reported cases where nanoparticles formed aggregates[22].Judging from FESEM and TEM images, it should be noted that the coverage density of Fe 3 O 4 NPs being assembled on the PU nanofibers is directly proportional to the amount of redispersed Fe 3 O 4 NPs in a polyol medium. Generally, in order to functionalize surface of electrospun nanofibers with metal or metal oxide nanoparticles, many of reports were used the immersion technique followed by post treatment in the presence of surfactant, sensitizing and stabilizing reagent[34][35][36]. However, here, our PU nanofibers have been completely covered by a sheath of densely packed Fe 3 O 4 NPs without using any additional chemicals to modify the nanofiber surfaces except of ethylene glycol dispersion medium.…”
“…For the samples of MNF 1 and MNF 2 , a large number of individual nanoparticles Fe 3 O 4 are anchored strongly and distributed homogenously on the surface of nanofiber, unlike in previously reported cases where nanoparticles formed aggregates[22].Judging from FESEM and TEM images, it should be noted that the coverage density of Fe 3 O 4 NPs being assembled on the PU nanofibers is directly proportional to the amount of redispersed Fe 3 O 4 NPs in a polyol medium. Generally, in order to functionalize surface of electrospun nanofibers with metal or metal oxide nanoparticles, many of reports were used the immersion technique followed by post treatment in the presence of surfactant, sensitizing and stabilizing reagent[34][35][36]. However, here, our PU nanofibers have been completely covered by a sheath of densely packed Fe 3 O 4 NPs without using any additional chemicals to modify the nanofiber surfaces except of ethylene glycol dispersion medium.…”
“…It should be noted that the TiO 2 rice-like distribution was reported to be a highly efficient coating mode because it highly increased the specific surface area of the coating layer with a TiO 2 size of ~30–50 nm [ 27 ]. The increase in the infrared extinction could be as high as 195 cm −1 .…”
Section: Resultsmentioning
confidence: 99%
“…The fourth mode is the rice-like geometry of the TiO 2 nanoparticles coated on the surface of electrospun fibers. For example, Zhao et al [ 27 ] prepared nylon 6 fibers with a TiO 2 rice-like coating and investigated their extinction capacities. The results indicated a high increase of almost 200 cm −1 in the extinction coefficient after the TiO 2 rice-like coatings.…”
Understanding the effect of a porous TiO2 nanolayer on the optical scattering and absorption through electrospun fibers is of great importance for the design and development of advanced optical extinction materials. Based on electrospinning and controllable self-assembly techniques, pure electrospun poly(vinylidene fluoride) (PVDF) fibers and TiO2-coated ones with different self-assembly cycles were prepared. The effect of TiO2 self-assembly cycles on surface parameters, e.g., thickness, assembled content, and porosity of the TiO2 nanolayer were determined by scanning electron microscopy, thermogravimetric analysis, and Fourier transform infrared spectroscopy. With an increase in the self-assembly cycles, the TiO2-coated electrospun PVDF fibers presented rougher surfaces and greater average diameters. According to the characterized surface parameters, the effects of the controllable self-assembly on the optical refractive index, absorption index, and infrared extinction were investigated to increase the optical properties of electrospun PVDF fibers. The results indicated that an increase of almost 120–130 cm−1 in infrared extinction could be achieved through the controllable self-assembly with only 5.7 wt. % assembled TiO2 content. This is highly efficient when compared with other coating modes. We believe that this study could give some positive guidance in the design of TiO2-coated electrospun fibers for improving their surface and optical properties.
“…Fibrous materials, especially nano‐fibers, have large surface areas. Coating such materials with metal or metal oxide can impact exceptional properties, such as catalysis, radiation shielding and antimicrobial 1–4. In particular, silver is a popular coating material because of its diverse applications, such as enhanced surface Raman scattering (SERS), antibacterial, and catalysis 1, 5–7.…”
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.