Electrospun nanofibre composite polymer electrolyte fuel cell and electrolysis membranes

Sood, Rakhi; Cavaliere, Sara; Jones, Deborah J.; Rozière, Jacqués

doi:10.1016/j.nanoen.2016.06.027

Cited by 138 publications

(90 citation statements)

References 143 publications

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“…Among these methods, the electrospinning (ES) process is of great importance due to the advantages of materials that can be utilized by it. For example, this method enables synthesis of fibers with large surface‐to‐volume ratio and mesoporous structure for various catalytic applications . In addition, ES is an attractive way to produce high‐surface‐area fibers with diameters in the nano–micrometer range and nonwoven nanofiber mats, with unique properties …”

Section: Introductionmentioning

confidence: 99%

Electrospun Ionomeric Fibers with Anion Conducting Properties

Mann‐Lahav

Halabi

Shter

et al. 2019

Adv Funct Materials

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Anion conductive nanofiber mats from FAA-3 ionomers are obtained by electrospinning. Depending on the solvent used in the precursor solution, nanofibers with either nonhollow cylindrical or flat ribbon-like cross-sections are prepared. The anion conductivity and water uptake of the ionomeric nanofiber mats are measured as a function of the relative humidity in the 10-90% range and compared to that of a solid membrane cast from the same ionomer. In addition, the anion conductivity of an isolated single fiber of the ionomer is measured for the first time. The anion conductivity of the electrospun single fiber is found to be higher than that of the mats, which is, in turn, one order of magnitude higher than that of the solid ionomer membrane. The higher conductivity of the mats relative to the solid membrane (in both inplane and through-plane directions) is found to be related to the variation in water uptake, which stems from the morphological distinctions. These results increase the understanding of the electrospinning process of ionomers, toward the development and design of new anion conductive ionomer fibers, useful for high performance electrochemical devices.

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Section: Introductionmentioning

confidence: 99%

Electrospun Ionomeric Fibers with Anion Conducting Properties

Mann‐Lahav

Halabi

Shter

et al. 2019

Adv Funct Materials

View full text Add to dashboard Cite

show abstract

“…In the last couple of years, researchers showed an increasing interest in electrospinning, a versatile technique which facilitates tailoring a broad range of organic polymers to fabricate thin fibers and fiber mats, amongst others for electrochemical energy applications . This efficient approach can be used to prepare high surface area electrodes of carbon nanofibers (CNFs) on a large scale, which then may be used in fuel cells, lithium ion or redox flow batteries . In our previous work, we demonstrated the use of electrospinning to prepare polyacrylonitrile (PAN)‐based CNFs and their successful application as free‐standing electrode for VRFBs.…”

Section: Introductionmentioning

confidence: 99%

Comparison of Electrospun Carbon−Carbon Composite and Commercial Felt for Their Activity and Electrolyte Utilization in Vanadium Redox Flow Batteries

et al. 2018

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A low cost highly active carbon−carbon composite fiber felt was produced by electrospinning a mixture of polyacrylonitrile and carbon black powder using poly acrylic acid as a binder for high carbon black loading. The newly designed high‐surface area electrode material showed promising results for use as electrode material for both the negative and positive half‐cell of vanadium redox flow batteries. Battery test results demonstrated promising performance for the electrospun carbon fibers at current densities below 60 mA cm−2, but were less active at higher values. The microstructure of the felt was characterized by X‐ray computed tomography to obtain the porous pathways, which facilitate electrolyte transport. The obtained results will help us to understand the role of porosity in the performance of the battery and to consequently improve the design of the carbon‐filled electrospun material.

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“…During recent decades, researchers have attempted to apply nanotechnology to various energy and power systems such as electric generators, fuel cells, batteries, and solar cells [1][2][3][4][5]. Nanotechnology has also been implemented to enhance the heat transfer potential of common liquids like water and oil to ameliorate the efficiency of thermal systems; this can be done through adding solid nanoparticles (particles with a size of 1-100 nm) to the liquids.…”

Section: -Introductionmentioning

confidence: 99%

Nanofluids effects on the evaporation rate in a solar still equipped with a heat exchanger

et al. 2017

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In this paper, the performance of a solar still equipped with a heat exchanger using nanofluids has been studied both experimentally and theoretically through three key parameters, i.e., freshwater yield, energy efficiency and exergy efficiency. First, experiments are performed on a set-up, which is mainly composed of two flat plate solar collectors connected in series, and a solar still equipped with a heat exchanger. After heated in the collectors, the nanofluid enters the heat exchanger installed in the solar still basin to exchange heat with brackish water. The research question is to know how much the effect of nanofluids on the evaporation rate inside the solar desalination system is. The experiments are conducted for different nanoparticle volume fractions, two sizes of nanoparticles (7 and 40 nm), two depths of water in the solar still basin (4 and 8 cm), and three mass flow rates of nanofluids during various weather conditions. It is found that the weather conditions (mainly the sun radiation intensity) have a dominant influence on the solar still performance. To discover the effects of nanofluids, a mathematical model is developed and validated by experimental data at given weather conditions. The results reveal that using the heat exchanger at temperatures lower than 60 o C is not advantageous and the corresponding yield is smaller than that of solar still without the heat exchanger; although in such a case, using 2 nanofluids as the working fluid in the heat exchanger can enhance the performance indices about 10%. At higher temperatures (e.g. 70 o C), the use of heat exchanger is beneficial; however, using nanofluids instead of water can augment the performance indices marginally i.e. just around 1%. In addition, it is found that in high temperatures using SiO 2 /water nanofluids, which have a lower effective thermal conductivity than that of Cu/water nanofluids, provides higher performance indices.Keywords: Nanofluids; Solar desalination; Heat exchanger; Freshwater yield 1-IntroductionNowadays, "Nano" and "Energy" have been two hot keywords, not only in the scientific community but also in our daily life. During recent decades, researchers have attempted to apply nanotechnology to various energy and power systems such as electric generators, fuel cells, batteries, and solar cells [1][2][3][4][5]. Nanotechnology has also been implemented to enhance the heat transfer potential of common liquids like water and oil to ameliorate the efficiency of thermal systems; this can be done through adding solid nanoparticles (particles with a size of 1-100 nm) to the liquids. The mixture of nanoparticles and conventional liquids is named "nanofluid" [6].Despite some limitations such as relatively high preparation cost and stability issues, extensive attempts have been made to develop the applications of nanofluids in energy systems such as solar energy based devices [7][8][9][10][11][12][13], cooling and thermal management of electronic equipment [14,15], grinding and drilling, absorption systems, medicine...

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Electrospun nanofibre composite polymer electrolyte fuel cell and electrolysis membranes

Cited by 138 publications

References 143 publications

Electrospun Ionomeric Fibers with Anion Conducting Properties

Electrospun Ionomeric Fibers with Anion Conducting Properties

Comparison of Electrospun Carbon−Carbon Composite and Commercial Felt for Their Activity and Electrolyte Utilization in Vanadium Redox Flow Batteries

Nanofluids effects on the evaporation rate in a solar still equipped with a heat exchanger

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