“…15–17 However, the PEC performance of CuWO 4 photoanodes is seriously impeded by the poor charge transfer and slow surface reaction kinetics. 18,19 Up to date, numerous strategies including controlling the morphology, 20 doping with exotic elements, 21 establishing heterojunctions, 22–24 loading with precious metals, 25 and incorporating with surface cocatalysts, 26 have been proposed to improve the PEC performance of CuWO 4 photoanodes. Particularly, constructing heterostructures with a built-in electric field is one of the most effective strategies to accelerate photogenerated charge separation and transfer.…”
Herein, we proposed the interfacial engineering of CuWO4/WO3 heterojunction to improve the photoelectrochemical (PEC) performance for solar water splitting. Our theoretical calculation reveals the greatly accelerated charge separation in CuWO4/WO3...
“…15–17 However, the PEC performance of CuWO 4 photoanodes is seriously impeded by the poor charge transfer and slow surface reaction kinetics. 18,19 Up to date, numerous strategies including controlling the morphology, 20 doping with exotic elements, 21 establishing heterojunctions, 22–24 loading with precious metals, 25 and incorporating with surface cocatalysts, 26 have been proposed to improve the PEC performance of CuWO 4 photoanodes. Particularly, constructing heterostructures with a built-in electric field is one of the most effective strategies to accelerate photogenerated charge separation and transfer.…”
Herein, we proposed the interfacial engineering of CuWO4/WO3 heterojunction to improve the photoelectrochemical (PEC) performance for solar water splitting. Our theoretical calculation reveals the greatly accelerated charge separation in CuWO4/WO3...
“…Nanoparticle modified nanofibers have been successfully applied in divergent areas such as catalysis [1][2][3], tissue engineering [4], photochemical applications [5][6][7], capacitors [8], energy applications [9], membrane electrodes in fuel cells [10], etc... Fuel cells (FC) are environmentally friendly alternative power sources [11] and until now from solid oxide to microbial FCs various studies have been reported which use the advantage of electrospun polymers [10,[12][13][14][15]. Electrospun polymers exhibit unique electrochemical activity.…”
Electrocatalytic effect of the untreated and TiO 2 +polyacrylonitrile (PAN) modified discarded battery coal (DBC) and pencil graphite electrodes (PGE) were evaluated in fuel cell (FC) applications. TiO 2 +PAN solution is coated on PGE and DBC electrodes by electrospinning. According to the FESEM and EDS characterizations, TiO 2 and PAN nanofibers are found to be approximately 40 and 240 nm sized. TiO 2 +PAN/PGE showed the best FC performances with 2.00 A cm-2 current density and 5.05 W cm-2 power density values, whereas TiO 2 +PAN/DBC showed 0.68 A cm-2 current density and 0.62 W cm-2 power density values. Electrochemical characterizations of PGE and TiO 2 +PAN/PGE electrodes were investigated by cyclic voltammetry and electrochemical impedance spectroscopy. Finally, long-term FC 2 measurement results of developed electrodes exhibited very reasonable recovery values. Along with the comparison of the electrode performances, the recovery of DBCs as electrodes for renewable energy production has been achieved.
“…[18,19] Up to date, to improve the PEC performance of CuWO 4 photoanodes, extensive research works focus on preparing CuWO 4 photocatalysts with different nanostructures or morphology by various chemical methods. [20][21][22][23] However, the resultant granular CuWO 4 photocatalysts in powder form not only complicate the fabrication of final photoanodes but also may limit their intrinsic photoelectrochemical activity for practical applications after fabricating into photoelectrodes by incorporating with binder and a conductive agent. As such, directly fabricating CuWO 4 film photoanodes with improved PEC performance will be more attractive and favorable for integrating into PEC devices toward practical applications.…”
CuWO 4 is a promising n-type oxide semiconductor for photoelectrochemical (PEC) applications due to the suitable band gap and good photochemical stability. An easy and large-scale fabrication of ultrathin CuWO 4 films with improved PEC performance is highly desired for future practical application but still challenging. Considering that the ultrasonic spray pyrolysis approach is a low-cost and scalable technique for fabricating films with controllable thickness, we here report the controllable fabrication of ultrathin CuWO 4 films with improved PEC performance by an automatic ultrasonic spray pyrolysis method. The effects of different tungsten sources and film thickness on the PEC performance of the resultant CuWO 4 film were studied in detail. We find that the ultrathin CuWO 4 film prepared from the ammonium metatungstate with a thickness of 2.16 μm shows the best PEC performance of 41 μA cm À 2 at 1.23 V vs.RHE for water oxidation under visible light irradiation. We also explored the different charge transfer mechanism and PEC performance of the resultant CuWO 4 films under back and front illumination.
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