2008
DOI: 10.1002/adfm.200701137
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Electrophosphorescent Polyfluorenes Containing Osmium Complexes in the Conjugated Backbone

Abstract: Electrophosphorescent copolymers have been synthesized by covalent bonding of a red‐emitting osmium complex Os(bpftz), which contains two 3‐trifluoromethyl‐5‐(4‐tert‐butyl‐2‐pyridyl)triazolate (bpftz) cyclometalated ligands, into the backbone of a bipolar polyfluorene (PF) copolymer. Employing these copolymers, a highly efficient red polymer light‐emitting diode has been realised that has an external quantum efficiency of 18.0%, a maximum brightness of 38 000 cd m−2, and an emission centered at 618 nm. In addi… Show more

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Cited by 87 publications
(48 citation statements)
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References 51 publications
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“…The PL of the copolymer is slightly blueshifted red-emitting P152 (Scheme 9.60) [170]. Highly efficient red-emitting PLED based on this polymer that exhibits an external quantum efficiency of 18.0% was realized.…”
Section: Polyfluorene Copolymers With Pt(ii) Re(i) Ru(ii) and Os(imentioning
confidence: 93%
“…The PL of the copolymer is slightly blueshifted red-emitting P152 (Scheme 9.60) [170]. Highly efficient red-emitting PLED based on this polymer that exhibits an external quantum efficiency of 18.0% was realized.…”
Section: Polyfluorene Copolymers With Pt(ii) Re(i) Ru(ii) and Os(imentioning
confidence: 93%
“…The efficiencies of WOLED based on Os-3 climbed up to 40.4 cd/A and 25.6 lm/W when it was doped with blue phosphor FIrpic [54]. Shu, Chi, and Chou synthesized a series of electrophosphorescent copolymers, in which a red-emitting Os(II) complex was embedded in the backbone of polyfluorene, giving a highly efficient PLED with maximum η ext of 18.0 % and maximum brightness of 38,000 cd/m 2 with an emission centered at 618 nm [55]. Furthermore, through covalent attachment of a low concentration of a green-emitting benzothiadiazole unit in the same polymers, efficient WOLED with η L of 10.7 cd/A and η ext of 5.4 % was achieved.…”
Section: Pt-gementioning
confidence: 99%
“…High efficiencies have been found for white emitting copolymers bearing phosphorescent complexes in the main chain or as pendant groups [32,33]. For instance low Fig.…”
Section: Approach (4): Woleds Based On Polymers Bearing Multiple Colomentioning
confidence: 99%