Electrophoretic mobility and stability of SiO₂ nanoparticles in the solutions of AOT in n‐hexadecane‐chloroform mixtures

Abstract

Electrophoretic mobility of SiO2 nanoparticles in a n‐hexadecane‐chloroform mixture depending on AOT concentration and chloroform content was determined. It was shown that an increase in chloroform content and a decrease in AOT concentration cause a growth in electrophoretic mobility. The use of the values of Debye lengths (characteristic thickness) of the diffuse part of the electric double layer (EDL) that were determined previously allowed us to calculate the electrokinetic potential and to evaluate the stability of organosols. The obtained data were in good correlation with the dynamics of temporal changes of hydrodynamic radius and the intensity of light scattering. Organosols may be used for heteroaggregation (sorption) of Au and Ag nanoparticles on SiO2.