Surface decoration of metal oxides
by metals for enhancing their
electrocatalytic properties for organic conversions has attracted
a lot of researchers’ interest due to their high abundancy,
inexpensiveness, and high stability. In the present work, a process
for the synthesis of black gold (BG) using a citrate assisted chemical
route and m-ZrO2 by a hydrothermal method at 200 °C
has been developed. Further, different concentrations of black gold
are being used to decorate the surface of zirconia by exploitation
of surface potential of zirconia and gold surfaces. The catalyst having
6 mol % concentration of black gold shows excellent electrocatalytic
activity for ethanol oxidation with low oxidation peak potential (1.17
V) and high peak current density (8.54 mA cm–2).
The current density ratio (j
f
/j
b
) is also high (2.54) for this catalyst indicating
its high tolerance toward poisoning by intermediate species generated
during the catalytic cycle. The enhanced electrocatalytic activity
can be attributed to the high tolerance of gold toward CO poisoning
and high stability of the ZrO2 support. The black gold
decorated zirconia catalyst showed enhanced activity during photoelectrochemical
studies when the entire spectrum of light falls on the catalyst. Ultrafast
transient studies demonstrated plasmonic excitation of metallic free
electrons and subsequent charge separation in the black gold–ZrO2 heterointerface as the key factor for enhanced photoelectrocatalytic
activity.