In
stacks of two-dimensional crystals, mismatch of their lattice
constants and misalignment of crystallographic axes lead to formation
of moiré patterns. We show that moiré superlattice effects
persist in twisted bilayer graphene (tBLG) with large twists and short
moiré periods. Using angle-resolved photoemission, we observe
dramatic changes in valence band topology across large regions of
the Brillouin zone, including the vicinity of the saddle point at
M
and across 3 eV from the Dirac points.
In this energy range, we resolve several moiré minibands and
detect signatures of secondary Dirac points in the reconstructed dispersions.
For twists θ > 21.8°, the low-energy minigaps are not
due
to cone anticrossing as is the case at smaller twist angles but rather
due to moiré scattering of electrons in one graphene layer
on the potential of the other which generates intervalley coupling.
Our work demonstrates the robustness of the mechanisms which enable
engineering of electronic dispersions of stacks of two-dimensional
crystals by tuning the interface twist angles. It also shows that
large-angle tBLG hosts electronic minigaps and van Hove singularities
of different origin which, given recent progress in extreme doping
of graphene, could be explored experimentally.