Electron spin resonance study of kinetics in the SRN1 reaction of aryl halides with potassium

Márquez, O. P.; Giulianelli, James; Wallace, Thomas C.; Eargle, D. Hoye

doi:10.1021/jo00866a047

J. Org. Chem.

1976

DOI: 10.1021/jo00866a047

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Electron spin resonance study of kinetics in the SRN1 reaction of aryl halides with potassium

O. P. Márquez¹,

James Giulianelli²,

Thomas C. Wallace³

et al.

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Cited by 6 publications

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“…Biphenyl halides were used to determine their electronic affinities by pulse techniques (7,8) because of their ability to exchange electrons. Most of the literature published about this topic refers to nonelectrodic reductions (9)(10)(11)(12)(13)(14)(15)(16)(17).…”

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confidence: 99%

Electrochemical Behavior of the Mono‐Substituted Biphenyl Halides in Dry Acetonitrile: Part I

Márquez

1986

J. Electrochem. Soc.

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Kinetic parameters for the anodic oxidation of biphenyl halides were determined in dry acetonitrile and tetra-nbutylammonium tetrafluoroborate on a platinum electrode. Single and double potential step chronoamperometry allowed the calculation of heterogeneous rate constants for the first voltammetric wave. The values of the rate constants, according to the substituting halide, showed the sequence: F < C1 < Br < I. Half-peak potentials were found to be well correlated to the values obtained for the rate constants as well as to the calculated Hfickel molecular orbital (HMO) energies. An estimate of ionization potentials was made from the correlation between half-wave potentials and HMO energies. ) unless CC License in place (see abstract). ecsdl.org/site/terms_use address. Redistribution subject to ECS terms of use (see 157.182.150.22 Downloaded on 2015-04-13 to IP Vol. 133, No. 9 BIPHENYL HALIDES OXIDATION 1819 ) unless CC License in place (see abstract). ecsdl.org/site/terms_use address. Redistribution subject to ECS terms of use (see 157.182.150.22 Downloaded on 2015-04-13 to IP

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Electrochemical Behavior of the Mono‐Substituted Biphenyl Halides in Dry Acetonitrile: Part I

Márquez

1986

J. Electrochem. Soc.

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Heavier alkali metals

Kaiser

1979

Journal of Organometallic Chemistry

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Heavier alkali metals

Kaiser

1977

Journal of Organometallic Chemistry

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Electron spin resonance study of kinetics in the SRN1 reaction of aryl halides with potassium

Cited by 6 publications

References 1 publication

Electrochemical Behavior of the Mono‐Substituted Biphenyl Halides in Dry Acetonitrile: Part I

Electrochemical Behavior of the Mono‐Substituted Biphenyl Halides in Dry Acetonitrile: Part I

Heavier alkali metals

Heavier alkali metals

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