Electron spin resonance of t-alkyl-, silyl-, and germyl-aminyl radicals and some observations on the amides MBr{N(SiMe3)2}3(M = Ge, Sn, or Pb)

Gumrukçu, I.; Hudson, Andrew; Läppert, Michael F.; Slade, Martin J.; Power, Philip P.

doi:10.1039/c39800000776

Cited by 21 publications

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“…It has been suggested that the shortening of the Si-N bonds and opening of the Si-N-Si angle in parent silylamides is due to dp-pp interactions, and some experimental evidence for such interactions from EPR spectroscopy has been observed. 16 A later computational study, however, suggested that independently of whether d orbitals of silicon are included in theoretical calculations, the structure of a related N(SiH 3 ) 3 is invariably predicted as planar, and therefore it is not specifically due to the d orbitals of silicon. 17 Our calculations at the B3LYP/3-21G* level predict that the spin density is the largest on nitrogen in bis(di-tert-butylsilyl)aminyl radical, 0.855, with only marginal delocalisation into neighbouring silicons, −0.05.…”

Section: Resultsmentioning

confidence: 99%

Unusual structural and energetic features of homolytic bond dissociation: from tetrakis(disyl)diphosphine to tetrakis(di-tert-butylsilyl)hydrazine

Borisenko

Rankin

2005

Dalton Trans.

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Quantum chemical calculations of the structures and thermodynamics of homolytic dissociation of the central P-P and N-N bonds in tetrakis(disyl)diphosphine and tetrakis(di-tert-butylsilyl)hydrazine have been performed. The theory predicted negative standard enthalpies for homolytic bond dissociation in both cases, -71.0 and -108.4 kJ mol(-1) for the diphosphine and hydrazine, respectively, using the ONIOM (MP2/6-31+G*:B3LYP/3-21G*) level. The dissociation is accompanied by considerable structural changes in the radicals as compared to the corresponding fragments of the parent molecules, resulting in low dissociation enthalpies. The most pronounced changes in both radicals are the relaxation of bond angles in the substituents and a conformational change in the orientation of the substituent groups. In addition, the bis(di-tert-butylsilyl)aminyl radical displays a considerable increase in Si-N-Si angle and shortening of the Si-N bonds upon dissociation. These changes are not associated with any appreciable delocalisation of the lone electron, as the spin density is found from the B3LYP/3-21G* calculations to be largely concentrated on the nitrogen atom. It has been also shown that although the dissociation energies are low for both compounds, the intrinsic energies of the central bonds are still high, 140.6 kJ mol(-1) for the P-P bond in tetrakis(disyl)diphosphine and 490.6 kJ mol(-1) for the N-N bond in tetrakis(di-tert-butylsilyl)hydrazine, using the ONIOM method. The calculations predict that the dissociation of tetrakis(disyl)diphosphine would have negative free energy even without taking relaxation of the fragments into account, while the full potential of releasing about 306 kJ mol(-1) of energy stored in the ligands of tetrakis(di-tert-butylsilyl)hydrazine is only fully realised upon a considerable separation of the fragments.

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Section: Resultsmentioning

confidence: 99%