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UDC 543.4:551.44, 902.035:551.44 Bonnie A. B. Blackwell: Electron Spin Resonance (ESR) Dating in Karst Environments Electron spin resonance (ESR) dating has been developed for many materials, including hydroxyapatite in enamel, bone, and some fish scales, aragonite and calcite in travertine, molluscs, and calcrete, and quartz from ash, which have many potential applications in karst settings. Although the complexity of the signals in some materials has hampered routine application, research is solving these problems to make the method even more widely applicable. when tested against other dating techniques, age agreement has usually been excellent. Generally, the most reliable applications seem to be tooth enamel, some mollusc species, calcite deposits, and quartz minerals. ESR dating uses signals resulting from trapped charges created by radiation in crystalline solids. Ages are calculated by comparing the accumulated dose in the dating sample with the internal and external radiation dose rates produced by natural radiation in and around the sample. For fossils and authigenic minerals, no zeroing is necessary to obtain accurate ages. In sediment which contains reworked mineral clasts, ESR can be used to date the age of the mineral grain itself if it was not zeroed during erosion. For dating the sedimentation age, however, ESR signals must have been zeroed in order to give the correct age. High pressure, heating, and in some minerals, light exposure and grinding can zero an ESR signal, but some like hydroxyapatite have very high stability at surface temperatures. For materials that absorb uranium (U) during their burial history, such as teeth, bones, or mollusc shells, the age calculation considers their U uptake by cross calibrating with U series or U/Pb dating or by assuming different uptake models. Some difficulties in calculating the external dose rate can be overcome by applying the ESR isochron method, in which the sample acts as its own dosimeter. In open-air karst environments, changes in Izvleček UDK 543.4:551.44, 902.035:551.44 Bonnie A. B. Blackwell: Določanje starosti v krasu s pomočjo elektronske spinske resonance (ESR) Metoda ugotavljanja starosti s pomočjo elektronske spinske resonance (ESR), je bila razvita za najrazličnejše gradivo in snovi, vključno hidroksiapatit, emajl, kost, ribjo lusko, aragonit in kalcit v lehnjaku, školjčnih lupinah in kalcitnih skorjah, kremen v pepelu, kar vse nudi široke možnosti za uporabo v kraškem okolju. čeprav pestrost signalov v nekaterem gradivu ovira vsestransko uporabnost, raziskave rešujejo te težavein tako je ta metoda še bolj vsestransko uporabna. Ob primerjanju z drugimi tehnikami datacije, je ujemanje v starosti običajno odlično. Na splošno je ta metoda najbolj zanesljiva, če se uporablja za zobno sklenino, nekatere vrste školjk, odkladnine kalcita in minerale kremena. ESR metoda izkorišča za datiranje signale, ki so posledica napetosti, ki jih ustvarja sevanje v kristalih. Starost se preračuna s pomočjo primerjave ohranjene količine sevanja v vzorcu za da...
UDC 543.4:551.44, 902.035:551.44 Bonnie A. B. Blackwell: Electron Spin Resonance (ESR) Dating in Karst Environments Electron spin resonance (ESR) dating has been developed for many materials, including hydroxyapatite in enamel, bone, and some fish scales, aragonite and calcite in travertine, molluscs, and calcrete, and quartz from ash, which have many potential applications in karst settings. Although the complexity of the signals in some materials has hampered routine application, research is solving these problems to make the method even more widely applicable. when tested against other dating techniques, age agreement has usually been excellent. Generally, the most reliable applications seem to be tooth enamel, some mollusc species, calcite deposits, and quartz minerals. ESR dating uses signals resulting from trapped charges created by radiation in crystalline solids. Ages are calculated by comparing the accumulated dose in the dating sample with the internal and external radiation dose rates produced by natural radiation in and around the sample. For fossils and authigenic minerals, no zeroing is necessary to obtain accurate ages. In sediment which contains reworked mineral clasts, ESR can be used to date the age of the mineral grain itself if it was not zeroed during erosion. For dating the sedimentation age, however, ESR signals must have been zeroed in order to give the correct age. High pressure, heating, and in some minerals, light exposure and grinding can zero an ESR signal, but some like hydroxyapatite have very high stability at surface temperatures. For materials that absorb uranium (U) during their burial history, such as teeth, bones, or mollusc shells, the age calculation considers their U uptake by cross calibrating with U series or U/Pb dating or by assuming different uptake models. Some difficulties in calculating the external dose rate can be overcome by applying the ESR isochron method, in which the sample acts as its own dosimeter. In open-air karst environments, changes in Izvleček UDK 543.4:551.44, 902.035:551.44 Bonnie A. B. Blackwell: Določanje starosti v krasu s pomočjo elektronske spinske resonance (ESR) Metoda ugotavljanja starosti s pomočjo elektronske spinske resonance (ESR), je bila razvita za najrazličnejše gradivo in snovi, vključno hidroksiapatit, emajl, kost, ribjo lusko, aragonit in kalcit v lehnjaku, školjčnih lupinah in kalcitnih skorjah, kremen v pepelu, kar vse nudi široke možnosti za uporabo v kraškem okolju. čeprav pestrost signalov v nekaterem gradivu ovira vsestransko uporabnost, raziskave rešujejo te težavein tako je ta metoda še bolj vsestransko uporabna. Ob primerjanju z drugimi tehnikami datacije, je ujemanje v starosti običajno odlično. Na splošno je ta metoda najbolj zanesljiva, če se uporablja za zobno sklenino, nekatere vrste školjk, odkladnine kalcita in minerale kremena. ESR metoda izkorišča za datiranje signale, ki so posledica napetosti, ki jih ustvarja sevanje v kristalih. Starost se preračuna s pomočjo primerjave ohranjene količine sevanja v vzorcu za da...
Electron spin resonance (ESR) dating can date many materials, including hydroxyapatite in enamel and some fish scales, aragonite and calcite in corals, molluscs, some travertine and calcrete, and quartz from ash, fluvial deposits, and some flint. Dating studies using these materials have numerous potential applications in many varied Quaternary settings. ESR dating uses signals resulting from trapped charges created by radiation in crystalline solids. Ages are calculated by comparing the accumulated radiation dose in the dating sample with the internal and external radiation dose rates produced by natural radiation in and around the sample and produced by cosmic radiation. When compared to other dating techniques, age agreement has been excellent for teeth, corals, molluscs, and quartz. Recent improvements have included using a more complex modelling technique to calculate the cosmic dose rates and more detailed modelling techniques for dealing with variable external dose rates. Methods in development include using quartz from buried fluvial valleys to date geomorphic surfaces and using the signals in barnacles and benthic foraminifera for dating fossils or their associated sediment. New chronometer applications recently developed include using coral and mollusc dates to build sealevel curves and to monitor volcanic activity and tectonic uplift, using tooth and mollusc dates to assess water availability in deserts, and using isochron data to assess U uptake processes into teeth. When coupled with other geochemical and geomorphological techniques, ESR can provide the chronometric control to build paleoclimatic and other paleoenvironmental records. Many other applications are possible, from heating studies for artefacts to dating sulphates and other minerals on distant planets.
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