“…[7][8][9][10] Furthermore, an enhanced electron-phonon coupling may appear for 2D electronic phases at interfaces, if dispersive electronic states offer a large number of decay channels for transitions coupled to surface phonons. 3,4,11,12 All these effects can be rationalized as due to the formation of hybrid interface electronic states with strong surface localization, and thus an ideal 2D character, mainly due to the bonding between metallic states and adsorbate p orbitals. In particular, the formation of highly-dispersive electronic states with almost free-electron like parabolic dispersion is a common feature of 2D systems with high atomic number Z, as observed in Bi/Ag(100), 13 Bi/Ag(111), 1 Bi/Cu(111), 14,15 Sb/Cu(111), 15 Sb/Ag(111), 16 Pb/Ag(111), 2 and Bi/Si(111).…”