We have created multispecies Coulomb crystals in a linear Paul trap containing up to a few hundred ions of which more than 50% were cooled only sympathetically through the Coulomb interaction with laser-cooled Mg 1 ions. In an extreme case, one laser-cooled ion maintained order in a 15 ion string. Ion species segregation was obtained by radiation pressure. Previous experiments and molecular dynamics simulations suggest the temperature is 10 mK or lower. These results indicate that a wide range of atomic and molecular ions can be cooled and localized in linear Paul traps which is important for improvements in spectroscopic studies of such ions. [S0031-9007(99)08637-8] PACS numbers: 32.80.Pj, 42.50.Vk, 52.25.Wz Trapped ions, when cooled sufficiently, form spatially ordered structures (Coulomb crystals). For smaller crystals (typically #10 5 ions), where surface effects play a dominant role, shell and stringlike structures are the equilibrium states [1-3]. Molecular dynamics (MD) simulations of infinite one component plasmas predict a body centered cubic (bcc) structure [4] as the lowest energy state. By applying laser cooling, string and shell structures have been observed in both Paul and Penning traps by imaging the fluorescence from the ions [5][6][7][8][9][10][11], and recently bcc structures at the center of very large ion crystals in a Penning trap have been revealed by Bragg scattering techniques [12,13]. Since only ions with simple level schemes accessible to lasers can easily be laser cooled, most atomic ion species, and all molecular ions, due to their complex vibrational and rotational structure, are excluded from this type of cooling. Hence, to date only very few singly charged ion species have been laser cooled and crystallized. The equations of motion in both Penning and Paul traps allow, however, ions within a certain chargeto-mass ratio to be trapped simultaneously, which makes sympathetic cooling [14] through the Coulomb interaction possible.Several authors have previously investigated sympathetic cooling, where directly laser cooled ions were used to cool ions of a different species through mutual Coulomb interaction [9,[14][15][16][17]. In most of these experiments, the typically achieved temperatures of the sympathetically cooled ions were several hundred mK, which were too high for ordering of the whole plasma. In a ring-shaped [18] and a linear Paul trap [19] a few nonfluorescing sites in crystals consisting of laser cooled 24 Mg 1 were attributed to indirectly cooled impurity ions. Recently, a crystal consisting entirely of Ca 1 was observed to stay crystallized when some of the constituent ions were decoupled from the cooling laser by being optically pumped into a metastable dark state [9].In this Letter we report on formation of Coulomb crystals consisting of up to a few hundred ions in a linear Paul trap where the fraction of indirectly (sympathetically) cooled ions is greater than 50%. In one case particularly interesting for spectroscopy, 14 sympathetically cooled ions were maintained in...