Abstract. High spectral resolution and signal-to-noise observations of the absorption and emission line spectra in two postasymptotic-giant-branch (PAGB) stellar candidates, LSIV −12 111 and HD 314617 are discussed. The absorption line spectra have been analysed using non-LTE model atmosphere techniques to determine stellar atmospheric parameters and chemical compositions, both in absolute terms and relative to a standard star, HD 13841. The atmospheric parameters differ from previous estimates based on LTE model atmospheres, probably due to non-LTE effects. In turn these imply stellar masses that are generally larger than have been previously estimated. Both PAGB candidates have relative uniform underabundances of metals with mean values of −0.35 dex for LSIV −12 111 and −0.50 dex for HD 314617. Furthermore, their abundance patterns are remarkably similar to that observed for optically bright, F-type PAGBs. From the emission spectra, the plasma parameters and angular size of the circumstellar material are constrained, and these are consistent with previous estimates and with a PAGB evolutionary stage.