The accurate determination of atomic final states following nuclear β decay plays an important role in several experiments. In particular, the charge state distributions of ions following nuclear β decay are important for determinations of the β − ν angular correlation with improved precision. Beyond the hydrogenic cases, the decay of neutral 6 He presents the simplest case. Our measurement aims at providing benchmarks to test theoretical calculations. The kinematics of Li n+ ions produced following the β decay of 6 He within an electric field were measured using 6 He atoms in the metastable (1s2s, 3 S1) and in the (1s2p, 3 P2) states confined by a magneto-optical trap. The electron shake-off probabilities were deduced including their dependence on ion energy. We find significant discrepancies on the fractions of Li ions in the different charge states with respect to a recent calculation.