Electron-donor/acceptor properties of carbynes, carbenes, vinylidenes, allenylidenes and alkynyls as measured by electrochemical ligand parameters

Electrochemical and Computational Chemistry Study of Mn(β-diketonato)3 complexes

“…Values for the Mn III /Mn II couple are -0.520 and -0.632 V vs FcH/FcH + , in CH 3 CN and DCM respectively. However, when converting these experimental values to SHE as reference system [22], the values are similar within experimental accuracy: -0.100 and -0.106 vs SHE, in CH 3 CN and DCM respectively. This is in agreement with a polarographic and voltammetric study of (2) in a series of solvents [12].…”

A picolinate-N2 complex of rhenium, the first dinitrogen complex bearing a carboxylate or a N,O-ligand

“…Moreover, its E L value is also comparable to those of some alkynyl ligands, e.g. C"CPh À at trans-{OsCl(dppm) 2 } + (dppm = Ph 2 PCH 2 PPh 2 ) [16].…”

Effect of CO substitution on the redox properties of Fischer Mo(0) carbene complexes Mo(CO)5=C(Y)(2-Furyl), Y=OEt, NHCy or NH2

“…E pa (E pc ) = anodic (cathodic) peak potential and i pa (i pc ) = anodic (cathodic) peak current. E 0 (Fc/Fc + ) = 0.66(5) V vs SHE in [ n (Bu 4 )N][PF 6 ]/CH 3 CN [28]. Decamethyl ferrocene (Fc*, À0.508 V vs Fc/Fc + ) was used as internal standard.…”