1981
DOI: 10.1021/j150619a016
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Electron acceptor properties of excited trans-thioindigo

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Cited by 9 publications
(11 citation statements)
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“…No quenching by toluene ( E r = 1.97 V) has been observed, in contrast to the thioindigo compounds (22), the reduction potentials (-0.5 V) of which are slightly less negative than that of the indigo derivatives (-0.58 V).…”
Section: A Excited State Involved In the Isomerizationmentioning
confidence: 80%
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“…No quenching by toluene ( E r = 1.97 V) has been observed, in contrast to the thioindigo compounds (22), the reduction potentials (-0.5 V) of which are slightly less negative than that of the indigo derivatives (-0.58 V).…”
Section: A Excited State Involved In the Isomerizationmentioning
confidence: 80%
“…It is known that the isomerization of stilbenes results from a singlet excited state (10,16) and that for thioindigo derivatives, molecules which are closely related to the series studied here, it depends on the geometry of the starting material with the trans isomer undergoing a photoisomerization via the triplet excited state (17)(18)(19), while the reverse photochemical reaction occurs from the singlet state (20,21). When the c -, t isomerization of thioindigo derivatives was studied in a toluene-containing solution, the isomerization quantum yield was found to vary with the temperature and to reach a maximum value (ca.…”
Section: A Excited State Involved In the Isomerizationmentioning
confidence: 90%
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